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Catalytic Synthesis of Methyl Oleate by Mesoporous Sieve Nb2O5/SBA-15
LI Chun-jing, SHEN Jian, ZHANG Liang, WANG Chao
Nb2O5/SBA-15 catalyst was prepared by impregnation with mesoporous molecular sieve SBA-15 as the carrier, and characterized by XRD, BET and other methods. The results show that catalyst Nb2O5/SBA-15, a highly ordered two-dimensional hexagonal mesoporous structure,has larger specific surface area,pore size and pore volume. The catalytic capability of Nb2O5/SBA-15 was studied for esterification, and the optimum reaction conditions were found as follows:n(methanol)/n(oleic acid)=2∶1,reaction temperature 160 ℃,reaction time 4 h,ratio of catalyst to reaction 9.10%. Better reuse ability of Nb2O5/SBA-15 can be also obtained, which confirms Nb2O5/SBA-15 a suitable catalyst for the esterification.
2008, 28 (4):
9-12.
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