Journal of Liaoning Petrochemical University
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Research Progress and Application of Hydrogen Purification by Pressure Swing Adsorption
Shuo ZHANG, Qiang SONG, Yulong ZHANG, Jiali ZHANG, Qi SUN
Abstract534)   HTML42)    PDF (609KB)(571)      

As a new type of clean, carbon?free, sustainable and efficient energy source, hydrogen has great potential in the future energy mix. Hydrogen purification by pressure swing adsorption is the main separation technology for hydrogen production with high purity, low energy consumption and high degree of automation. In this paper the progress in research and application of pressure swing adsorption hydrogen production in theoretical simulation, process control optimization and adsorbent materials were critically reviewed, and the future development of pressure swing adsorption hydrogen production technology was prospected.

2023, 43 (6): 30-36. DOI: 10.12422/j.issn.1672-6952.2023.06.005
Research Progress of Grinding Technology with Minimum Quantity Lubrication
Jiaqi Zheng, Changfu Liu, Xiaodan Zhu, Yu Wang, Shuo Zhang
Abstract252)   HTML8)    PDF (1682KB)(308)      

Grinding technology with minimum quantity lubrication technology is a new type of environmentally friendly and efficient processing technology. It has the characteristics of less cutting fluid and low cutting force, and is conducive to the maintenance of the tool and can effectively improve the quality of the workpiece. However, the cooling performance of the high?pressure air flow of the grinding technology with minimum quantity lubrication is very limited, which can not meet the need for cooling in the grinding zone. The traditional casting cooling technology can meet this demand by using a large amount of grinding fluid. In this paper, the research background, development status and latest achievements of micro?lubrication technology were reviewed, which lays a theoretical foundation for further study of the characteristics and principles of these special grinding technology with minimum quantity lubrication..

2023, 43 (4): 84-91. DOI: 10.12422/j.issn.1672-6952.2023.04.013
Preparation and Characterization of Modified Ethylene Tar Pitch
Shuo Zhang, Huaijia Fu, Dongyun Han, Haiyan Qiao, Weiwei Shi, Xiaodan Deng
Abstract283)   HTML9)    PDF (1938KB)(241)      

The effects of polymerization reaction temperature, polymerization reaction time, catalyst and crosslinker addition on the properties of modified ethylene tar pitch (METP) were investigated, and the optimal reaction conditions were obtained by combining elemental analysis, FT?IR, XRD, Raman and thermogravimetric analysis on ETP and METP: The polymerization reaction temperature was 370 ℃, and the polymerization reaction time was 6 h, besides the addition of catalyst and crosslinker was 1.50%. The softening point (SP) of METP obtained under these conditions was 182 ℃, the coking value (CV) was 57.66%, the β resin was 42.26%, and the quinoline insoluble matter (QI) was 0.87%, which met the requirements of high carbon material precursors; The yieid of METP was 73.26%.

2023, 43 (4): 8-13. DOI: 10.12422/j.issn.1672-6952.2023.04.002
Refining and Polymerization of Coking Coal Oil Fraction to Produce High Viscosity Base Oil
Shuo Zhang, Zewu Jiang, Fuzhi Jia, Jiarui Du, Weiwei Shi, Yuqi Zhang, Dongyun Han
Abstract275)   HTML11)    PDF (1869KB)(280)      

The coking kerosene fraction was used as the raw material for the experiment. The linear α?olefins in the raw oil were enriched by complex extraction method, and the high viscosity poly α?olefin base oil (PAO) was synthesized by oligomerization. The effects of temperature, time and catalyst dosage on the properties of PAO were investigated. The kinematic viscosity, viscosity index and PAO yield rate at 100 ℃ were determined. Under the optimum process conditions of catalyst mass fraction of 6%, polymerization temperature of 25 °C, polymerization time of 8.0 h, addition polymerization temperature of 80 °C and addition polymerization time of 2.0 h, the reaction effect is the best: The kinematic viscosity of PAO at 100 ℃ is 43.54 mm2/s, the viscosit index is 163, the freezing point is -50 ℃, and the flash point is 291 ℃. The yield is 85.48%. Compared with the PAO40 standard, the obtained product is a high viscosity lube base oil.

2023, 43 (3): 21-27. DOI: 10.12422/j.issn.1672-6952.2023.03.004