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Research on the Construction of CdS/Mg⁃CdIn 2S 4 Heterostructures and Their Catalytic Performance in CO 2 Photoreduction
Yan ZHANG, Zhengyi SONG, Liu WAN, Cheng DU, Mingjiang XIE, Jian CHEN
Abstract52)   HTML2)    PDF (3538KB)(0)      

CdS exhibits excellent photochemical properties and high quantum efficiency in the visible light region, however, its catalytic stability is significantly compromised by photocorrosion. Constructing CdS/Mg?CdIn2S4 heterojunctions can effectively suppress photocorrosion and enhance the material's overall stability. In this study, CdS nanowires (CdS NWs), CdS nanoparticles (CdS NPs), and Mg?CdIn2S4 nanosheets (NSs) were prepared using the ion exchange method, and heterojunctions of 5% CdS NWs/Mg?CdIn?S? (5% by mass fraction of CdS NWs) and 5% CdS NPs/Mg?CdIn?S? (5% by mass fraction of CdS NPs) were constructed. The photocatalysts were characterized using X?ray diffraction (XRD), UV?vis diffuse reflectance spectroscopy (DRS), Fourier?transform infrared (FT?IR) spectroscopy, N2 adsorption?desorption isothermal analysis, transient photocurrent measurements, and electrochemical impedance spectroscopy. The results confirmed the successful construction of both CdS NWs/Mg?CdIn2S4 and CdS NPs/Mg?CdIn2S4 heterojunctions. The catalytic performance was evaluated in a photoreaction system, both heterojunctions possess significant capabilities for the photocatalytic reduction of CO2. Notably, the CdS NWs/Mg?CdIn2S4 heterojunction exhibited superior photocatalytic performance, achieving CO and H2 production rates of 716.7 μmol/(g·h) and 664.3 μmol/(g·h), respectively. These values represent a 46.2?fold and 56.8?fold enhancement compared to pristine Mg?CdIn?S?.Consequently, this work provides a solid foundation for further research and practical applications in the field of photocatalytic CO2 reduction, underscoring significant academic and practical significance.

2025, 45 (5): 28-36. DOI: 10.12422/j.issn.1672-6952.2025.05.004
Research on Extraction of Land Use Status Information from Remote Sensing Images Based on CA-Res2-Unet
Caihua SUN, Yang CAO, Hongfei YU, Xuejian CHEN
Abstract1461)   HTML23)    PDF (3916KB)(313)      

The combination of remote sensing image information extraction and artificial intelligence algorithms is an important technical tool for land use status survey, monitoring and management in land resources and environmental departments.Aiming at the problems of insufficient spatial information localization and inaccurate multi-scale target feature segmentation generated by U-net in remote sensing image extraction, a CA-Res2-Unet model incorporating an attention module into the head of Res2Net to replace the coding part of U-net is proposed, which aims to enhance the spatial localization and multi-scale feature information segmentation capability of U-net.Experiments were carried out on mainstream networks and improved models through the WHDLD public data set and the self-made data set of Shenfu New District. The results show that compared with the basic model, OA, MIoU and F1 indexes of the experiment on the WHDLD public data set and the self-made data set of Shenfu New District increased by 0.92%, 2.00%, 1.58% and 1.18%, 2.87%, 1.91%, respectively. The visual effect and quantitative indexes of the proposed method are superior to other mainstream semantic segmentation networks, which can provide scientific basis for the investigation of the status quo of regional land use and the decision-making of relevant departments.

2024, 44 (3): 89-96. DOI: 10.12422/j.issn.1672-6952.2024.03.012