Journal of Liaoning Petrochemical University
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Study of Process Condition and Kinetics of Hydrodesulfurization of Low-Quality Diesel Oil

Guo Yuanqi, Liu Dong, Gao Yuan, Ao Hongwei, Wang Shubo, Li Qingyun, Yan Feng
Abstract555)      PDF (1936KB)(415)      

he hydrogen desulfurization of four kinds of low-quality diesel oils using HPL-1 as was studied on a smallsized hydrogenation unit. The reaction kinetics and the effects of reaction temperature, reaction pressure, volume space velocity and volumetric hydrogen/oil ratio on desulfurization rate have been investigated. The results showed the optimal hydrodesulfurization condition as follows: reaction temperature 360 , pressure 7.0 MPa, space velocity 1.0h-1, and volumetric hydrogen/oil ratio 800:1. Under this condition, the lowquality diesel desulfurization rate can be reached up to 9657%. Moreover, a 0.5 order kinetic model for lowquality diesel was setabilished based on the factors of pressure, hydrogen/oil ratio and space velocity parameters correction. The results indicate that the experimental values and simulation values are in good coincide for four kinds of low-quality diesel sulfur content.

2016, 36 (3): 15-19. DOI: 10.3969/j.issn.1672-6952.2016.03.004