Journal of Liaoning Petrochemical University

Journal of Liaoning Petrochemical University ›› 2014, Vol. 34 ›› Issue (4): 9-12.DOI: 10.3696/j.issn.1672-6952.2014.04.003

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Removal of Propanal from HighPressure Polyethylene Return Gas by Adsorption with Activated Carbon

Xu Kaixiong1, 2, Wu Shikui2, Wang Xiaoning 1   

  1. (1.Liaoning Shihua University, Fushun Liaoning 113001, China; 2.Guangdong University of Petrochemical Technology, Maoming Guangdong 525000, China)
  • Received:2013-03-13 Published:2014-08-25 Online:2017-07-14

活性炭吸附脱除高压聚乙烯装置返回气中丙醛的研究

徐开雄1, 2,吴世逵2,王晓宁1   

  1. ( 1. 辽宁石油化工大学, 辽宁抚顺1 1 3 0 0 1; 2. 广东石油化工学院, 广东茂名5 2 5 0 0 0)
  • 通讯作者: 王晓宁( 1 9 7 2 - ) , 男, 博士, 副教授, 从事石油化工节能研究; E - m a i l : w x n i n g 3 3 3@1 6 3. c o m。
  • 作者简介:徐开雄( 1 9 8 8 - ) , 男, 硕士研究生, 从事石油化工节能研究; E - m a i l : x u k a i x i o n g 2 0 0 8@1 2 6. c o m。
  • 基金资助:
    中石化茂名分公司科技攻关项目( 2 0 1 2 4 4 0 9 1 0 0 0 0 0 0 4) 。

Abstract: The removal of propanal from high pressure return gas by adsorbing with activated carbon has been carried out. The effect of temperature and feed gas velocity on the removal rate and breakthrough curve has been studied, and the recycled sorbents by different recycling methods were also evaluated. The experimental results show that removing rate of propanal was the highest at 30 ℃. The removing rate of propanal maintained between 70%~90% at the feed gas flow of 30 mL/min. After active carbon adsorbed for 570 minutes, the removing rate of propanal has dropped to about 30% and reached to its adsorption saturation. The removal rate of propanal was above 95% after recycling activated carbon for 3 times at 120 ℃ by steam, which is better method compared with N2blowing method and heating in vacuum.

Key words: Active Carbon, Propanal, Ethelene, Adsorption, Desorption

摘要:  研究了活性炭吸附脱除高压聚乙烯装置返回气中的丙醛, 考察了温度和原料气流速对脱醛率的影响和活性炭吸附丙醛的吸附穿透曲线, 同时比较了活性炭在不同脱附方法脱附后再吸附丙醛的情况。实验结果表明,温度对活性炭的脱醛率有影响, 3 0℃时脱醛率最高; 在原料气流速为3 0mL /m i n时, 丙醛的脱除率为7 0%~9 0%;
活性炭吸附5 7 0m i n后, 丙醛的脱除率下降到3 0%左右; 采用1 2 0℃水蒸气脱附法, 活性炭三次吸附的脱醛率都在9 5%以上, 好于加热氮气吹扫脱附法和加热抽真空脱附法。

关键词: 活性炭 ,  丙醛 ,  , 乙烯 ,  吸附 ,  , 脱附

Cite this article

Xu Kaixiong, Wu Shikui, Wang Xiaoning. Removal of Propanal from HighPressure Polyethylene Return Gas by Adsorption with Activated Carbon[J]. Journal of Liaoning Petrochemical University, 2014, 34(4): 9-12.

徐开雄,吴世逵,王晓宁. 活性炭吸附脱除高压聚乙烯装置返回气中丙醛的研究[J]. 辽宁石油化工大学学报, 2014, 34(4): 9-12.