Preparation and Characterization of Modified Ethylene Tar Pitch

doi:10.12422/j.issn.1672-6952.2023.04.002

Journal of Liaoning Petrochemical University ›› 2023, Vol. 43 ›› Issue (4): 8-13.DOI: 10.12422/j.issn.1672-6952.2023.04.002

• Chemistry and Chemical Engineering • Previous Articles Next Articles

Preparation and Characterization of Modified Ethylene Tar Pitch

Shuo Zhang¹(), Huaijia Fu², Dongyun Han¹(), Haiyan Qiao¹, Weiwei Shi¹, Xiaodan Deng³

^1.School of Petrochemical Technology，Liaoning Petrochemical University，Fushun Liaoning 113001，China
^2.Zibo Qixiang Tengda Chemical Co. ，Ltd. ，Zibo Shandong 255438，China
^3.China Kunlun Contracting ＆ Engineering Corporation Shenyang Company，Shenyang Liaoning 110015，China

Received:2023-03-03 Revised:2023-03-23 Published:2023-08-25 Online:2023-09-04
Contact: Dongyun Han

改性乙烯焦油沥青的制备及表征分析

张硕¹(), 付怀佳², 韩冬云¹(), 乔海燕¹, 石薇薇¹, 邓小丹³

^1.辽宁石油化工大学石油化工学院，辽宁抚顺 113001
^2.淄博齐翔腾达化工股份有限公司，山东淄博 255438
^3.中国昆仑工程有限公司沈阳分公司，辽宁沈阳 110015

通讯作者: 韩冬云
作者简介:张硕（1998⁃），男，硕士研究生，从事清洁燃料生产方面的研究；E⁃mail：dashuo1002@163.com。
基金资助:
辽宁省教育厅科学研究项目(LJKZ0409)

Abstract

Abstract:

The effects of polymerization reaction temperature, polymerization reaction time, catalyst and crosslinker addition on the properties of modified ethylene tar pitch (METP) were investigated, and the optimal reaction conditions were obtained by combining elemental analysis, FT?IR, XRD, Raman and thermogravimetric analysis on ETP and METP: The polymerization reaction temperature was 370 ℃, and the polymerization reaction time was 6 h, besides the addition of catalyst and crosslinker was 1.50%. The softening point (SP) of METP obtained under these conditions was 182 ℃, the coking value (CV) was 57.66%, the β resin was 42.26%, and the quinoline insoluble matter (QI) was 0.87%, which met the requirements of high carbon material precursors； The yieid of METP was 73.26%.

Key words: ETP, Thermal polymerization, METP, β resin, Yield

摘要：

以乙烯焦油沥青（ETP）为原料，对其进行热聚合改性处理，探讨了聚合反应温度、聚合反应时间、催化剂及交联剂质量分数对改性乙烯焦油沥青（METP）的组成、性质及收率的影响，并结合元素分析、FT?IR、XRD、Raman、热重分析对ETP及METP进行研究，得到了最佳反应条件：聚合反应温度为370 ℃，聚合反应时间为6 h，催化剂和交联剂质量分数为1.50%。在此条件下得到的METP的软化点（SP）为182 ℃，结焦值（CV）为57.66%，β树脂质量分数为42.26%，喹啉不溶物（QI）质量分数为0.87%，符合高碳材料前驱体的要求；METP收率为73.26%。

关键词: 乙烯焦油沥青, 热聚合, 改性乙烯焦油沥青, β树脂, 收率

CLC Number:

TE65

Shuo Zhang, Huaijia Fu, Dongyun Han, Haiyan Qiao, Weiwei Shi, Xiaodan Deng. Preparation and Characterization of Modified Ethylene Tar Pitch[J]. Journal of Liaoning Petrochemical University, 2023, 43(4): 8-13.

张硕, 付怀佳, 韩冬云, 乔海燕, 石薇薇, 邓小丹. 改性乙烯焦油沥青的制备及表征分析[J]. 辽宁石油化工大学学报, 2023, 43(4): 8-13.

Figures/Tables 11

References 20

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样品	SP/℃	质量分数/%				碳氢原子比	w(CV)/%	w(灰分)×10/%
样品	SP/℃	C	H	O	其他	碳氢原子比	w(CV)/%	w(灰分)×10/%
ET	-	91.34	7.63	0.18	0.85	0.997	14.60	0.05
ETP	110	92.81	5.94	1.17	0.08	1.302	38.70	0.05

样品	SP/℃	质量分数/%				碳氢原子比	w(CV)/%	w(灰分)×10/%
样品	SP/℃	C	H	O	其他	碳氢原子比	w(CV)/%	w(灰分)×10/%
ET	-	91.34	7.63	0.18	0.85	0.997	14.60	0.05
ETP	110	92.81	5.94	1.17	0.08	1.302	38.70	0.05

样品	w(C)/%	w(H)/%	w(O)/%	w(其他)/%	碳氢原子比
ETP	92.81	5.94	1.17	0.08	1.30
METP	94.06	5.32	0.59	0.03	1.47

样品	w(C)/%	w(H)/%	w(O)/%	w(其他)/%	碳氢原子比
ETP	92.81	5.94	1.17	0.08	1.30
METP	94.06	5.32	0.59	0.03	1.47

样品	I_g/%	L_C/nm	d₀₀₂/nm	N	n	（I_G/I_all）/%	（I_D2/I_G）/%
ETP	62.12	0.212	0.393	1.54	0.76	0.25	0.29
METP	69.48	0.232	0.383	1.61	0.83	0.29	0.21

Preparation and Characterization of Modified Ethylene Tar Pitch

改性乙烯焦油沥青的制备及表征分析

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