Preparation and Photocatalytic Properties of Nanocarbon Particles/Carbon Nitride

doi:10.3969/j.issn.1672-6952.2021.04.007

Journal of Liaoning Petrochemical University ›› 2021, Vol. 41 ›› Issue (4): 41-45.DOI: 10.3969/j.issn.1672-6952.2021.04.007

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Preparation and Photocatalytic Properties of Nanocarbon Particles/Carbon Nitride

Huaichuan Shi(), Lei Shi()

School of Petrochemical Engineering，Liaoning Petrochemical University，Fushun Liaoning 113001，China

Received:2020-09-10 Revised:2020-10-13 Published:2021-08-25 Online:2021-09-16
Contact: Lei Shi

纳米碳颗粒/氮化碳复合材料的制备及光催化性能

石怀川(), 石磊()

辽宁石油化工大学石油化工学院，辽宁抚顺 113001

通讯作者: 石磊
作者简介:石怀川（1999⁃），男，本科生，复合材料与工程专业，从事光催化剂的制备及性能方面的研究；E⁃mail：167065367@qq.com。
基金资助:
辽宁省教育厅基本科研项目(L2020038);辽宁省大学生创新创业计划项目(201910148040)

Abstract

Abstract:

Nanocarbon particles/carbon nitride composite was prepared through one step heat polymerization method. XRD, FTIR, TEM, UV?vis DRS, PL and other methods were used to systematically characterize nanocarbon particles/carbon nitride. Rhodamine B solution was degraded to measure its photocatalytic performance. The results show that the loading of nanocarbon particles can obviously improve visible light absorbed ability of the composite material and the separation efficiency of photogenerated electrons/holes. When the added mass of nanocarbon particles is 10 mg, the rhodamine B degradation rate of as?prepared nanocarbon particles/carbon nitride 2 is 96.5% in the 20 min, which is obviously better than bare carbon nitride. In addition, nanocarbon particles/carbon nitride composites show good stability.

Key words: Carbon nitride, Nanocarbon particles, Photocatalysis, Pollutants degradation, Visible light

摘要：

通过一步热聚合法制备纳米碳颗粒/氮化碳复合材料，利用XRD、FTIR、TEM、DRS、PL等手段对纳米碳颗粒/氮化碳进行了系统表征，并考察其光催化降解罗丹明B的光催化性能。结果表明，纳米碳颗粒的负载可以显著改善复合材料的可见光吸收能力及光生电子/空穴的分离效率，当加入纳米碳颗粒的质量为10 mg时，所得到的纳米碳颗粒/氮化碳2在20 min内对罗丹明B的降解率可以达到96.5%，明显优于纯氮化碳材料。此外，纳米碳颗粒/氮化碳复合材料还表现出良好的稳定性。

关键词: 氮化碳, 纳米碳颗粒, 光催化, 污染物降解, 可见光

CLC Number:

O643.3

Huaichuan Shi, Lei Shi. Preparation and Photocatalytic Properties of Nanocarbon Particles/Carbon Nitride[J]. Journal of Liaoning Petrochemical University, 2021, 41(4): 41-45.

石怀川, 石磊. 纳米碳颗粒/氮化碳复合材料的制备及光催化性能[J]. 辽宁石油化工大学学报, 2021, 41(4): 41-45.

Figures/Tables 9

References 16

1	Chen X， Mao S S， Titanium dioxide nanomaterials： Synthesis， properties， modifications， and applications［J］. Chemical Reviews， 2007， 107： 2891⁃2959.
2	Hoffmann M R， Martin S T， Choi W， et al. Environmental applications of semiconductor photocatalysis［J］. Chemical Reviews， 1995， 95： 69⁃96.
3	Niu M， Huang F， Cui L， et al. Hydrothermal synthesis， structural characteristics， and enhanced photocatalysis of SnO₂/α⁃Fe₂O₃ semiconductor nanoheterostructures［J］. ACS Nano， 2010， 4： 681⁃688.
4	Shekofteh⁃Gohari M， Habibi⁃Yangjeh A， Abitorabi M， et al. Magnetically separable nanocomposites based on ZnO and their applications in photocatalytic processes： A review［J］. Critical Reviews in Environmental Science and Technology， 2018， 48： 806⁃857
5	汪军，王毓芳，徐伯兴. ZnO光催化降解苯酚的试验研究［J］. 污染防治技术，1999，12（2）：98⁃100.
6	Wang X C， Maeda K， Thomas A， et al. A metal⁃free polymeric photocatalyst for hydrogen production from water under visible light［J］. Nature Materials， 2009， 8： 76⁃80
7	Ma J， Wang C， He H. Enhanced photocatalytic oxidation of NO over g⁃C₃N₄⁃TiO₂ under UV and visible light［J］. Applied Catalysis B， 2016， 184： 28⁃34.
8	Fageria P， Nazir R， Gangopadhyay S， et al. Graphitic⁃carbon nitride support for the synthesis of shape⁃dependent ZnO and their application invisible light photocatalysts［J］. RSC Advances， 2015， 5（98）： 80397⁃80409.
9	Ge L， Zuo F， Liu J， et al. Synthesis and efficient visible light photocatalytic hydrogen evolution of polymeric g⁃C₃N₄ coupled with CdS quantum dots［J］. The Journal of Physical Chemistry C， 2012， 116（25）： 13708⁃13714.
10	Li M， Zhang L， Wu M， et al. Mesostructured CeO₂/g⁃C₃N₄ nanocomposites： Remarkably enhanced photocatalytic activity for CO₂ reduction by mutual component activations［J］. Nano Energy， 2016， 19： 145⁃155.
11	Ye L Q， Liu J Y， Jiang Z， et al. Facets coupling of BiOBr⁃g⁃C₃N₄ composite photocatalyst for enhanced visible⁃light⁃driven photocatalytic activity［J］. Applied Catalysisi B Environmental， 2013， 142⁃143（10）： 1⁃7.
12	Wang W J， Cheng H F， Huang B B， et al. Hydrothermal synthesis of C₃N₄/BiOIO₃ heterostructures with enhanced photocatalytic properties［J］. Journal of Colloid and Interface Science， 2015， 442： 97⁃102.
13	An X Q， Yu J C. Graphene⁃based photocatalytic composites［J］. RSC Advances， 2011， 1（8）： 1426⁃1434.
14	Xu T， Zhang L， Cheng H， et al. Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study［J］. Applied Catalysisi B Environmental， 2011， 101（3⁃4）： 382⁃387.
15	Sun Z， Guo J， Zhu S， et al. A high⁃performance Bi₂WO₆⁃graphene photocatalyst for visible light⁃induced H₂ and O₂ generation［J］. Nanoscale， 2014， 6： 2186⁃2193.
16	Shi L， Liang L， Wang F， et al. In situ bubble template promoted facile preparation of porous g⁃C₃N₄ with excellent visible⁃light photocatalytic performance［J］. RSC Advances， 2015， 5（78）： 63264⁃63270.

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Preparation and Photocatalytic Properties of Nanocarbon Particles/Carbon Nitride

纳米碳颗粒/氮化碳复合材料的制备及光催化性能

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References 16

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