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Particle Velocity Distribution in the Bubbling Fluidized Bed
YANG Kuan-li, WANG Qi-cheng, ZHANG Kai,DAI Wei-di,JIANG Jian-chun
Abstract429)      PDF (3355KB)(511)      
 
Radial velocity distributions of two kinds of glass beads, belonging to Geldart type B classification, were investigated at different axial sections in the bubbling fluidized bed with an inner diameter of 0.185 m under different superficial gas velocities. Local particle velocities were measured by using the PV-5A fiber-optical probe. The experimental results indicate that the radial distribution of particle velocities in the bed bottom zone is irregular, where the design of the distributor is dominated. When the axial section is far from the distributor, the particle velocities are higher in the center than those near the wall within the bed, which becomes obvious with increasing superficial gas velocity. Meanwhile, there exists a transitional zone between the above two zones, where the effect of the distributor tends to be weakened. This leads that the radial distribution of particle velocities is regular. Moreover, the amplitude of particle velocity at the same axial position changes sharply with an increase of superficial gas velocity.
2008, 21 (3): 5-8.
H 2-TG for Tungsten Phosphide Catalyst Precursors
LI Cui -qing, SUN Gui-da, JIANG Jian
Abstract216)      PDF (997KB)(193)      
Diammonium hydrogen phosphate and ammonium metatungstate were used to prepare WP precursor. The impregnation and mixing methods were used to prepare the WP/γ-Al 2O 3 precursor with loading of 30%(counting by WO 3) , respectively. WP/γ-Al 2O 3 precursors by adding some content of promoter Ni,Co,V with loading of 30%(counting by WO 3) were also prepared with impregnation method, respectively. All catalysts were measured with thermogravimetric(TG)analysis in H 2 flow. The synthetic process of WP catalyst was studied. The effect of synthetic method and promoter on phosphiding extent of WP/γ-Al 2O 3 precursor was investigated. The results show that WP precursor can be reduced to WP completely in H 2 flow. W species on the surface of WP/γ-Al 2O 3 precursors prepared by impregnation or mixing methods can not be reduced to WP completely in H 2 flow . A substance with a similar structure of -Al-O-W-P is probably formed on the support surface. Compared with WP/γ-Al 2O 3 precursor by mixing method, W species is more difficult to be reduced to WP on the surface of WP/γ-Al 2O 3 precursor by impregnation method. It suggests that inginating reduced temperature of WP/γ-Al 2O 3 precursor is obviously decreased by adding promoter nickel(Ni). Cobalt(Co) increases the phosphiding extent of WP/γ-Al 2O 3 precursor. Adding vanadium(V) species on the surface of WP/γ-Al 2O 3 precursor is more different to be reduced to WP.
2007, 20 (4): 16-20.