Journal of Petrochemical Universities

Journal of Petrochemical Universities ›› 2013, Vol. 26 ›› Issue (5): 23-26.DOI: 10.3969/j.issn.1006396X.2013.05.006

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Preparation of Hierarchical Porous ZnLa/HZSM5 Zeolite  and Its Application in Methanol Aromatization

  

  1. (1.College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun Liaoning 113001, China; 2. PetroChina Fushun Petrochemical Company Refinery No.2, Fushun Liaoning 113004, China; 3. College of Shunhua Energy, Liaoning Shihua University, Fushun Liaoning 113001, China)
  • Received:1900-01-01 Revised:1900-01-01 Published:2013-10-25 Online:2013-10-25

多级孔ZnLa/HZSM-5制备及在甲醇芳构化中的应用

孙志岩1,赵伟林2,胡志君2,张玲3,赵岑1,王海彦1*   

  1. (1.辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001;2.中国石油抚顺石化公司石油二厂,辽宁抚顺113004;3.辽宁石油化工大学顺华能源学院,辽宁抚顺113001)
  • 作者简介:孙志岩(1986),男,辽宁朝阳市,在读硕士。
  • 基金资助:
    辽宁省自然科学基金资助项目(201202126)。

Abstract: The alkaline treatment of ZSM5 zeolite with NaOH solution, received the hierarchical porous ZSM5 zeolite, Zn and La by coimpregnation method of loading in the alkali treatment of the modified ZSM5 zeolite, the ZSM5 molecular sieves were characterized by XRD, BET,SEM and NH3TPD. The reaction of methanol aromatization was investigated in a fixed bed reactor. The results show that after alkali treatment modified ZSM5 zeolite had a pore size increased and the acidity distribution was changed; ZnLa/HZSM5 zeolite had the better catalytic, Zn and La with the load capacity of each of 0.5%, the reaction temperature was 475 ℃, the reaction pressure was 0.6 MPa, LHSV was 0.8 h-1, the yield of aromatic hydrocarbons (benzene, toluene and xylene) up to 32.3%.

Key words: Hierarchical porous material,    ,  ZSM5 zeolite,    ,  Methanol,    ,  Aromatization,   ,  Zn,   ,  La

摘要: 采用NaOH 溶液对ZSM灢5分子筛进行碱处理,制备了多级孔径ZSM灢5分子筛。采用浸渍法制备了多级孔Zn灢La/HZSM灢5分子筛,并采用XRD、BET、SEM 和NH3灢TPD等方法进行了表征,在固定床反应器中进行甲醇芳构化反应。结果表明,经过碱处理,ZSM灢5分子筛的平均孔径、孔容和比表面积增大,孔径呈微孔和介孔多级孔分布。Zn和La的负载量均为0.5%时,Zn灢La/ZSM灢5分子筛具有较好的芳构化活性。在反应温度475 曟、反应压力0.6MPa、空速(LHSV)0.8h-1条件下,芳烃(苯、甲苯和二甲苯)的收率可达32.3%。

关键词: 多级孔,    , ZSM-5分子筛,    , 甲醇,    , 芳构化,    , 锌,    ,

Cite this article

SUN Zhiyan,ZHAO Weilin,HU Zhijun,et al. Preparation of Hierarchical Porous ZnLa/HZSM5 Zeolite  and Its Application in Methanol Aromatization[J]. Journal of Petrochemical Universities, 2013, 26(5): 23-26.

孙志岩,赵伟林,胡志君. 多级孔ZnLa/HZSM-5制备及在甲醇芳构化中的应用[J]. 石油化工高等学校学报, 2013, 26(5): 23-26.