Journal of Petrochemical Universities

Journal of Petrochemical Universities ›› 2013, Vol. 26 ›› Issue (3): 13-17.DOI: 10.3969/j.issn.1006396X.2013.03.004

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Synthesis of WaterSoluble NitrogenContaining Calixarene

  

  1. School of Chemistry and Materials Science, Liaoning Shihua University, Fushun Liaoning 113001, China
  • Received:2013-02-25 Published:2013-06-25 Online:2013-06-25

水溶性含氮杯芳烃的合成

张亚洲,刘丽梅,臧树良,陈平*   

  1. (辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001)
  • 作者简介:张亚洲(1986-),男,辽宁阜新市,在读硕士。
  • 基金资助:
    教育部科学技术研究重点项目(209031)。

Abstract: Calix [4] arene was synthesized by dealkylation reaction using ptertbutylcalix [4] arene and phenol as raw material in the presence of anhydrous AlCl3. Then 5,11,17,23four sulfo phenyl)azo calix [4] arene was synthesized by coupling reaction using calix [4] arene and pamino benzene sulfonic acid as raw materials. In the presence of tinhydrochloric acid, 5,11,17,23four sulfo phenyl)azo calix [4] arene was reduced to 5,11,17,23four aminocalix [4] arene hydrochloride. The synthesized compounds were characterized by thermal analysis, infrared spectrum analysis and UV spectra of the synthesized compounds. By using the method of synthesis of calix [4] arene ammonium hydrochloride yield is high, cost is greatly reduced.

Key words: Calixarene,    , Watersoluble,    , Synthesis,    , Azo,    , Reduction,   , Calixarene amine hydrochloride

摘要: 以对叔丁基杯[4]芳烃为原料,在无水三氯化铝存在下,与苯酚发生脱烷基化反应合成了杯[4]芳烃。 再以杯[4]芳烃与对氨基苯磺酸为原料,通过偶合反应合成了5,11,17,23灢四[(对磺基苯基)偶氮]灢杯[4]芳烃,再利 用锡灢盐酸还原得到5,11,17,23灢四氨基灢杯[4]芳烃盐酸盐。合成的化合物通过热分析、红外光谱和紫外光谱等对合成的各化合物分析。利用该方法合成杯[4]芳烃铵的盐酸盐收率高,成本大大降低。

关键词: 杯芳烃 , 水溶性 , 合成 , 偶氮 , 还原 , 杯芳烃铵盐酸盐

Cite this article

ZHANG Yazhou, LIU Limei, et al. Synthesis of WaterSoluble NitrogenContaining Calixarene[J]. Journal of Petrochemical Universities, 2013, 26(3): 13-17.

张亚洲,刘丽梅,臧树良,陈平. 水溶性含氮杯芳烃的合成[J]. 石油化工高等学校学报, 2013, 26(3): 13-17.