Journal of Petrochemical Universities

Journal of Petrochemical Universities ›› 2012, Vol. 25 ›› Issue (4): 14-17.DOI: 10.3969/j.issn.1006-396X.2012.04.004

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The Performance of H2S Adsorbed on the Face of Fe(OH)3

  

  1. 1.School of Chemistry and Material Science, Liaoning Shihua University, Fushun Liaoning 113001, P.R. China;  2.School of Environmental and Biological Engineering, Liaoning Shihua University, Fushun Liaoning 113001, P.R. China
  • Received:2012-03-27 Published:2012-08-25 Online:2012-08-25

低浓度H2S在Fe(OH)3 表面的吸附反应研究

刘博1,张金辉2,张振华1* ,商丽艳2,张凤华1,杨成龙2   

  1. 1.辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001;2.辽宁石油化工大学环境与生物工程学院,辽宁抚顺113001
  • 作者简介:刘博(1987-),男,辽宁抚顺市,在读硕士
  • 基金资助:
    国家自然科学基金资助项目(21171083)

Abstract: The adsorption reaction between active sulfur - take H2S for example - at a low concentration and Fe(OH)3 the corrosion product on the inner face of refining device was investigated. The effect of temperature, humidity of H2S gas and humidity of Fe(OH)3 was discussed. The results show that with the increasing of temperature, humidity of H2S gas and humidity of Fe(OH)3, the adsorption tendency increases.

Key words: font-size: 10.5pt, mso-bidi-font-size: 11.0pt, mso-ascii-theme-font: minor-latin, mso-fareast-font-family: 宋体, mso-fareast-theme-font: minor-fareast, mso-hansi-theme-font: minor-latin, mso-bidi-font-family: 'Times New Roman', mso-bidi-theme-font: minor-bidi, mso-ansi-language: EN-US, mso-fareast-language: ZH-CN, mso-bidi-language: AR-SA" lang="EN-US"> Active sulfur,    ,  Refining device,    ,  Adsorption reaction

摘要:  以活性硫HS为例,研究低浓度时与炼油装置内表面腐蚀产物Fe(OH)的表面吸附反应过程,考察温度、反应气体相对湿度、Fe(OH)含水率对吸附反应的影响,旨在为炼油厂抑制因活性硫腐蚀产物引发的自燃事故提供依据。研究结果表明,温度升高,有利于吸附反应,反应气体相对湿度及Fe(OH)含水率的增加均促进吸附反应。

关键词: 活性硫 , 炼油装置 , 吸附反应

Cite this article

LIU Bo, ZHANG Jin-hui, ZHANG Zhen-hua,et al. The Performance of H2S Adsorbed on the Face of Fe(OH)3[J]. Journal of Petrochemical Universities, 2012, 25(4): 14-17.

刘博,张金辉,张振华,商丽艳. 低浓度H2S在Fe(OH)3 表面的吸附反应研究[J]. 石油化工高等学校学报, 2012, 25(4): 14-17.