Journal of Petrochemical Universities

Journal of Petrochemical Universities ›› 2010, Vol. 23 ›› Issue (3): 21-25.DOI: 10.3696/j.issn.1006-396X.2010.03.005

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Synthesis and Performance of High Branch Polyether Demulsifiers

  

  1. College of Chemistry and Chemical Engineering, Daqing Petroleum Institute, Daqing Heilongjiang 163318,P.R.China
  • Received:2010-01-29 Revised:2010-04-04 Published:2010-09-25 Online:2010-09-25

一种高支化聚醚破乳剂的合成及性能研究

王 俊胡凤莲曲红杰李翠勤   

  1. 大庆石油学院化学化工学院, 黑龙江大庆163318
  • 作者简介:王俊(1965 -), 男, 黑龙江泰来县, 教授, 博士
  • 基金资助:
    黑龙江省博士后资助项目(LRB08-131)

Abstract:

The phenol-amine resin was synthesized through dehydration condensation reaction of bisphenol A, diethylenetriamine and formaldehyde at reaction temperature 70 ℃, reaction time 60 min and the post treatment was 120 ℃, 1.33 kPa. PAE polyether demulsifiers with different EO mass fraction and mass ratio of initiator to PO were synthesized through reactions with different proportions of propylene oxide and ethylene oxide using phenol-amine resin as initiator. The characterization of PAE demulsifiers was studied by surface tension measurement and UV-vis spectra method. The results show that within low concentrations the ability of decreasing surface tension increased with decreasing EO mass fraction and increasing mass ratio of initiator to PO; the efficiency of decreasing surface tension increases with increasing mass ratio of initiator to PO and decreasing EO mass fraction. From the demulsification experiments a conclusion has been drawn that the final dehydration rate of demulsifiers increased with increasing mass fraction of EO; the speed of reaching dehydration platform is faster for the demulsifier with high mass ratio of initiator to PO. Dehydration rate of 80% is observed at 40 ℃,15 min and dosage 20 mg/L for PAE84, and there is no demulsification effect for SP169 at the same condition.

Key words: High branch moleculers , Polyether , Surface tension , Demulsifier

摘要:

以双酚A、甲醛和二乙烯三胺为原料,在70 ℃下反应60 min,再在120 ℃,1.33 kPa下脱水缩合得到酚胺树脂,然后以酚胺树脂为起始剂,与PO、EO反应合成了6种具有十八分支的PAE聚醚破乳剂。测定了所合成聚醚的表面张力及紫外吸收光谱。结果表明,PAE聚醚破乳剂降低表面张力的能力随EO质量分数的降低和起始剂与PO质量比的升高而增强;降低临界胶团浓度的能力随起始剂与PO质量比的增加及EO质量分数的降低而增强。室内评价表明,PAE聚醚破乳剂的最终脱水率随EO质量分数增加而升高,起始剂与PO质量比高的破乳剂脱水速度快。PAE84在40 ℃,加量20 mg/L时,15 min脱水率即达到80%,而相同条件下SP169基本无破乳效果。
 

关键词: 高支化分子 , 聚醚 , 表面张力 , 破乳剂

Cite this article

WANG Jun, HU Feng-lian, QU Hong-jie, LI Cui-qin . Synthesis and Performance of High Branch Polyether Demulsifiers[J]. Journal of Petrochemical Universities, 2010, 23(3): 21-25.

王 俊,胡凤莲,曲红杰,李翠勤. 一种高支化聚醚破乳剂的合成及性能研究[J]. 石油化工高等学校学报, 2010, 23(3): 21-25.