Effect of Graphene Doping on Electrochemical Performance of Cathode Materials of Ternary Sodium⁃Ion Batteries

doi:10.12422/j.issn.1006-396X.2023.06.007

Abstract

Abstract:

In recent years, the research of sodium?ion batteries has received more and more attention, and transition metal oxides are considered to be the most potential cathode material system for industrialization due to their easy preparation, low cost, high capacity and high electrochemical activity. As the cathode material of ternary transition metal oxide sodium?ion battery, NaFe_1/3Ni_1/3Mn_1/3O₂ further improves the electrochemical performance of cathode materials on the basis of existing monic materials and binary materials. In this paper, the influence of conductive nanomaterial modification on its electrochemical performance was studied using ternary metal oxide NaFe_1/3Ni_1/3Mn_1/3O₂ as a model, and a doping strategy was provided to improve the cathode material performance of ternary transition metal oxide sodium?ion batteries.

Key words: Sodium?ion battery, Cathode materials, Transition metal oxides, Ternary materials, Graphene

摘要：

近年来，钠离子电池的研究受到了越来越多的关注，过渡金属氧化物因易制备、低成本、高容量和高电化学活性等优点，被认为是最有潜力实现产业化的钠离子电池正极材料。NaFe_1/3Ni_1/3Mn_1/3O₂作为三元过渡金属氧化物钠离子电池正极材料，在已有的一元材料、二元材料的基础上，进一步提高了正极材料的电化学性能。以三元金属氧化物NaFe_1/3Ni_1/3Mn_1/3O₂为模型，研究了导电纳米材料改性对其电化学性能的影响，提供了提升三元过渡金属氧化物钠离子电池正极材料性能的掺杂策略。

关键词: 钠离子电池, 正极材料, 过渡金属氧化物, 三元材料, 石墨烯

CLC Number:

TQ152

Liuyang HE, Xiaojie LI, Chan WANG, Chunyang DUAN. Effect of Graphene Doping on Electrochemical Performance of Cathode Materials of Ternary Sodium⁃Ion Batteries[J]. Journal of Petrochemical Universities, 2023, 36(6): 64-72.

贺柳洋, 李晓杰, 王婵, 段春阳. 石墨烯掺杂对三元钠离子电池正极材料电化学性能的影响[J]. 石油化工高等学校学报, 2023, 36(6): 64-72.

Figures/Tables 11

Fig.1 Schematic diagram of a sodium?ion battery half?cell

Fig.2 SEM of NaFe1/3Ni1/3Mn1/3O2，Gr and composites and EDS of composites

Fig.3 XRD of NaFe1/3Ni1/3Mn1/3O2, Gr and composites

Fig.4 FTIR of NaFe1/3Ni1/3Mn1/3O2, Gr and composites

Fig.5 XPS of NaFe1/3Ni1/3Mn1/3O2@0.5%Gr

Fig.6 TGA curves of NaFe1/3Ni1/3Mn1/3O2、Gr and composites

Fig.7 Cyclic voltammetry curves of NaFe1/3Ni1/3Mn1/3O2 and composites

Fig.8 EIS diagram of NaFe1/3Ni1/3Mn1/3O2 and composites

Fig.9 Charge and discharge profiles of NaFe1/3Ni1/3Mn1/3O2 and composites in the first cycle

Fig.10 Cycle performance plot of NaFe1/3Ni1/3Mn1/3O2 and composites during 100 cycles

Fig.11 Rate performance of NaFe1/3Ni1/3Mn1/3O2 and composites

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