石油化工高等学校学报

石油化工高等学校学报 ›› 2013, Vol. 26 ›› Issue (1): 21-24.DOI: 10.3969/j.issn.1006396X.2013.01.005

• 石油化工 • 上一篇    下一篇

硫酸氢盐离子液体萃取氧化脱硫研究

肖晶1,王强1,2,周明东1,颜文超1,臧树良1,2*   

  1. (1.辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001;2.华东师范大学化学系,上海200062)
  • 收稿日期:2012-09-06 出版日期:2013-02-25 发布日期:2013-02-25
  • 作者简介:肖晶(1988飊),女,吉林松原市,在读硕士。
  • 基金资助:
    国家自然科学基金资助项目(21071073,
    21101085);中国石油天然气股份有限公司资助
    项目(20110906)。

Extractive and Oxidative Desulfurization of Fuel Oils Using Hydrosulfate Based Ionic Liquids

  1. 1. College of Chemistry and Material Science, Liaoning Shihua University, Fushun Liaoning 113001, China;  2. Department of Chemistry, East China Normal University, Shanghai 200062, China
  • Received:2012-09-06 Published:2013-02-25 Online:2013-02-25

PDF

摘要： 合成了一系列烷基碳链长度不同的1烷基3甲基咪唑硫酸氢盐离子液体，以质量分数为35% 的H2O2为氧化剂，考察了萃取时间、剂油体积比、温度等不同条件对模拟油品的脱硫效果，确定了最佳脱硫实验条件；在最佳实验条件下，考察反应体系对FCC汽油、柴油的脱硫效果。结果表明，［C3mim］HSO4离子液体的脱硫效果最好。在V(［C3mim］HSO4 ) / V(H2O2) / V(模型油)=1∶1∶30，60 ℃的条件下反应90 min，对模拟油品及实际油品均有较高的脱硫率，对模拟油品一次脱硫率为88.38%，对抚顺石化公司石油二厂的FCC柴油的一次脱硫率在80%以上，FCC汽油经一次脱硫后，硫的质量分数下降至10 μg/g以下，显示了很高的工业应用前景。

关键词: 硫酸氢盐离子液体, 氧化脱硫;暋萃取 , FCC汽油 , FCC柴油

Abstract: A series of Nmethylimidazolium hydrosulfate type of ionic liquids (ILs) bearing different length of alkyl chains were synthesized. The ionic liquids were applied both as extracting reagent and catalyst for the model or true oil desulfurization using hydrogen peroxide (35%) as the oxidant. The desulfurization conditions were optimized by varying extraction time, the ratio of ILs/oil, temperature and so on. Under the optimal conditions, the ILs were also used for the desulfurization of FCC gasoline and diesel. The results show that, ［C3mim］HSO4 has the highest desulfurization rate. The best desulfurization rate was obtained after 1.5 hours under the condition of V(［C3mim］HSO4)/V(H2O2 )/V(oil)=1∶1∶30 at 60 ℃ for the model oil (88.38%) and diesel (80%). The sulfur content of FCC gasoline has decreased to 10 μg/g below, which shows a very promising perspective for industrial applications.

Key words: Hydrosulfate based ionic liquids,    ,  Oxidative desulfurization,    , Extraction,    , Fluid catalytic cracking gasoline,    ,  Fluid catalytic cracking diesel

引用本文

肖晶,王强,周明东,颜文超,臧树良. 硫酸氢盐离子液体萃取氧化脱硫研究[J]. 石油化工高等学校学报, 2013, 26(1): 21-24.

XIAO Jing,WANG Qiang,ZHOU Mingdong,et al. Extractive and Oxidative Desulfurization of Fuel Oils Using Hydrosulfate Based Ionic Liquids[J]. Journal of Petrochemical Universities, 2013, 26(1): 21-24.

使用本文

0
    /   /   推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal.lnpu.edu.cn/syhg/CN/10.3969/j.issn.1006396X.2013.01.005

               http://journal.lnpu.edu.cn/syhg/CN/Y2013/V26/I1/21



网站版权 © 2021《石油化工高等学校学报》编辑部

本系统由北京玛格泰克科技发展有限公司设计开发