石油化工高等学校学报

石油化工高等学校学报 ›› 2013, Vol. 26 ›› Issue (3): 53-56.DOI: 10.3969/j.issn.1006396X.2013.03.012

• 化工机械 • 上一篇    下一篇

肉桂醛与3-甲基-4-氨基-5-巯基-1,2,4-均三唑复配对碳钢的缓蚀协同效应

王舒青1,吕振波1,杨鹏2,刘丹1* ,桂建舟1,曹淑云1,王普军1,王兴之1   

  1. (1.辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001;2.沈阳药科大学制药工程学院,辽宁沈阳110016)
  • 收稿日期:2013-01-17 出版日期:2013-06-25 发布日期:2013-06-25
  • 作者简介:王舒青(1984-),女,内蒙古呼和浩特市,在读硕士。
  • 基金资助:
    国家自然科学基金项目(21103077);教育部新世
    纪优秀人才支持计划(NCET-11-1011);教育部重
    点项目(209031);辽宁省高等学校杰出青年学者
    成长计划(LJQ2011035);辽宁省自然基金
    (201102120,201202123)。

Synergistic Inhibition Effect on CarbonSteel between Cinnamaldehyde  and 3Methy4Amino5Mercapto1,2,4Triazole

  1. (1. College of Chemistry and Material Science, Liaoning Shihua University, Fushun Liaoning 113001, China; 2.School Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang Liaoning 110016, China)
  • Received:2013-01-17 Published:2013-06-25 Online:2013-06-25

摘要: 分别采用极化曲线、交流阻抗和静态失重等方法研究了肉桂醛与3-甲基-4-氨基-5-巯基-1,2,4-均三唑(简称为MACMT)复配对Q235碳钢在不同浓度盐酸介质中的缓蚀效果。并探讨了缓蚀剂浓度对缓蚀性能的影响及其缓蚀机理。结果表明,肉桂醛与3-甲基-4-氨基-5-巯基-1,2,4-均三唑均为1mmol/L时对Q235碳钢在0.5、1、2mol/LHCl介质中均有很好的缓蚀效果,缓蚀率达93%以上,两者复合后有良好的协同效应。盐酸介质温度的升高对缓蚀性能影响较小。

关键词: 肉桂醛 , Q235碳钢 , 协同效应, 缓蚀剂

Abstract: The synergistic inhibition effect between cinnamaldehyde and 3methy4amino5mercapto1,2,4triazole(short for MACMT)on Q235 steel in the HCl solution was studied by polarization curves, EIS and immersion. The influence of concentration on the corrosion performance and inhibition mechanism was discussed. The experiments show that when both cinnamaldehyde and 3methy4amino5mercapto1,2,4triazole were 1 mmol/L inhibiting system proposed good synergistic effect, inhibition efficiency could improve to more than 93%, on the Q235 steel in 0.5 mol/L HCl, 1 mol/L HCl, 2 mol/L HCl solution. In addition, increasing temperature exerted small influence on the inhibition efficiency.

Key words: Cinnamaldehyde,    , Q235 carbonsteel,    ,  Synergistic inhibition effect,    ,  Inhibitor

引用本文

王舒青,吕振波,杨鹏,刘丹,桂建舟. 肉桂醛与3-甲基-4-氨基-5-巯基-1,2,4-均三唑复配对碳钢的缓蚀协同效应[J]. 石油化工高等学校学报, 2013, 26(3): 53-56.

WANG Shuqing,LYU Zhenbo,, YANG Peng,et al. Synergistic Inhibition Effect on CarbonSteel between Cinnamaldehyde  and 3Methy4Amino5Mercapto1,2,4Triazole[J]. Journal of Petrochemical Universities, 2013, 26(3): 53-56.

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