石油化工高等学校学报

石油化工高等学校学报 ›› 2011, Vol. 24 ›› Issue (5): 14-16.DOI: 10.3696/j.issn.1006-396X.2011.05.004

• 石油化工 • 上一篇    下一篇

高凝点原油降凝剂的研制与复配

王景昌,赵建涛,杜中华,刘春明   

  1. (大连大学环境与化学工程学院,辽宁大连116622)
  • 收稿日期:2011-09-16 修回日期:2011-10-08 出版日期:2011-10-25 发布日期:2011-10-25
  • 作者简介:王景昌(1964-),男,辽宁大连市,教授,博士。
  • 基金资助:
    国家自然科学基金项目(20676022)。

Preparation of a Composite Pour Point Depressant for High Crud Oil

  1. College of Environmental and Chemical Engineering, Dalian University, Dalian Liaoning 116622,P.R.China
  • Received:2011-09-16 Revised:2011-10-08 Published:2011-10-25 Online:2011-10-25

摘要: 在甲苯溶剂中引发聚合,由物质的量比6∶1∶2的丙烯酸十八酯、马来酸酐、苯乙烯合成降凝剂A,由物质的量比为6∶1∶2的丙烯酸十八酰胺、马来酸酐、苯乙烯合成降凝剂B。在甲苯溶剂中,120 ℃条件下用十八胺和十八醇分别对降凝剂A,B进行醇解和胺解合成降凝剂C和D。以大庆原油为样本考察了A,B,C,D的降凝和降粘效果。在大庆原油中加入质量分数0.5%的降凝剂进行测试,结果表明降凝剂C,D在降凝和降粘上都优于降凝剂A,B。复配性降凝剂C+D在降凝和降粘效果上高于降凝剂C,D。降凝剂C+D的复配质量比为3∶1时,可使大庆原油凝点降低15℃,粘度降低58.38%。

关键词: 共聚物, 降凝剂, 醇解, 胺解

Abstract: By the way of initiated polymerization in toluene solution,two tercopolymers were prepared from octadecyl acrylate(acrylamide),maleic anhydride and styrolene in molar ratio 6∶1∶2 as pour point depressant A(B),C(D),akind of pour point depressant,was synthesized by alcoholysis (aminolysis) of A(B) by stearyl alcohol(octadecylamine) in the toluene as solvent at 120 ℃.The drop effect of pour point and viscosity of A,B,C and D for the sample to Daqing crude oil was investigated.The study was tested by adding the pour point depressants A,B,C,D to high pour point crude oil of Daqing at a dosage of 0.5%,respectively.The results suggest that the pour point depressants of C & D are more effective than A & B,meanwhile,the combination C+ D is more effective than C and D.After adding C+D in mass ratio 3∶1 to Daqing crude oil, its pour point is lowered by 15℃ and viscosity could be reduced by 58.38%.

Key words: Polymer,     , Pour point depresant,    , Alcoholysis,    , Aminate

引用本文

王景昌,赵建涛,杜中华,刘春明. 高凝点原油降凝剂的研制与复配[J]. 石油化工高等学校学报, 2011, 24(5): 14-16.

WANG Jing-chang, ZHAO Jian-tao,DU Zhong-hua, LIU Chun-ming. Preparation of a Composite Pour Point Depressant for High Crud Oil[J]. Journal of Petrochemical Universities, 2011, 24(5): 14-16.

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