氧化石墨烯基复合薄膜材料的制备技术及应用进展

doi:10.12422/j.issn.1006-396X.2023.06.002

摘要/Abstract

摘要：

氧化石墨烯因其特殊的物理和化学性质成为近年来研究的热门材料，有关氧化石墨烯基复合薄膜材料的制备、功能化及应用成为当下的前沿和热门课题。综述了氧化石墨烯基复合薄膜材料的组装方法与性能研究，包括氧化石墨烯基复合Langmuir?Blodgett（LB）膜、氧化石墨烯基复合静电纺丝膜以及其他氧化石墨烯基复合薄膜，归纳总结了氧化石墨烯基复合膜近期的研究进展，并对其应用前景进行了展望。

关键词: 氧化石墨烯, Langmuir?Blodgett技术, 静电纺丝技术, 薄膜

Abstract:

Graphene oxide has become a popular material for research in recent years due to its unique physical and chemical properties. The preparation, functionalization, and application of graphene based composite membrane materials have become cutting?edge and popular topics. This article reviews the assembly methods and performance research of graphene oxide based composite membrane materials, including graphene oxide based composite Langmuir?Blodgett (LB) film, graphene oxide based composite electrospinning film, and other graphene oxide based composite films. It summarizes the recent research progress of graphene oxide based composite films and prospects their application prospects.

Key words: Graphene oxide, Langmuir?Blodgett technology, Electrospinning technology, Film

中图分类号:

TQ536.9

陶穆楠, 谷雯惠, 焦体峰. 氧化石墨烯基复合薄膜材料的制备技术及应用进展[J]. 石油化工高等学校学报, 2023, 36(6): 13-23.

Munan TAO, Wenhui GU, Tifeng JIAO. Preparation Technology and Application Progress of Graphene Oxide Based Composite Thin Film Materials[J]. Journal of Petrochemical Universities, 2023, 36(6): 13-23.

图/表 17

图1 样品制备过程示意图

Fig.1 Schematic diagram of the sample preparation

图2 独立GO?LbL膜的制作和组装示意图

Fig.2 Schematic representation of fabrication and assembly of free?standing GO?LbL membrane

图3 磷脂LB膜固定化青霉素酶原理图

Fig.3 Schematic diagram of immobilized penicillin enzyme on phospholipid LB membrane

图4 Langmuir?Blodgett实验装置示意图

Fig.4 Schematic of the Langmuir?Blodgett experimental setup

图5 通过静电纺丝技术制备的GO纳米纤维注：PAS溶液的质量浓度为20 g/L。

Fig.5 GO nanofibers fabricated by electrospinning

图6 静电纺丝技术制备GO掺杂PVDF/CuO/Al纳米复合材料的示意图

Fig.6 Schematic description of fabrication of GO?doped PVDF/CuO/Al nanocomposites via electrospinning

图7 纳米纤维膜制备流程

Fig.7 Nanofiber membrane preparation process

图8 PVP?PDA?GO纳米纤维在不同温度和pH下的热致变色行为

Fig.8 Color change behavior of PVP?PDA?GO nanofibers at different temperatures and pHs

图9 PVDF/石墨烯传感器的制备过程及实验结果

Fig.9 The procedure and experimental results for the fabrication of PVDF/graphene sensor

图10 PAN/GO/PI膜的制备工艺及静电纺丝溶液的成分

Fig.10 Fabrication process of PAN/GO/PI and components of electrospinning solutions

图11 通过动态静电纺丝系统制备PSA/G纳米复合材料的示意图

Fig.11 Schematic illustration of the fabrication of PSA/ graphene nanocomposites by dynamic electrospinningsystem

图12 PEO和GO基杂化Nafion纳米纤维膜的制备示意图

Fig.12 Schematic presentation for the fabrication of PEO? and GO?based hybrid Nafion nanofiber membranes

图13 具有抗菌活性的静电纺丝PU/GO伤口敷料示意图

Fig.13 Schematic of electrospinning PU/GO wound dressing with antibacterial activity

图14 GO/GOH复合膜的制备工艺示意图

Fig.14 Schematic of the fabrication process for the GO/GOH composite membranes

图15 通过旋涂辅助方法制造大面积石墨烯膜的示意图

Fig.15 Schematic illustration of the fabrication of large?area graphene membrane by the spin?coating?assisted method

图16 通过N2等离子体制备的N掺杂NGM

Fig.16 Fabrication of NGMs:N?doping introduced by N2 plasma treatment

图17 建议的GOHMFC结构

Fig.17 The structure of the suggested GOHMFC

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