辽宁石油化工大学学报

辽宁石油化工大学学报 ›› 2011, Vol. 31 ›› Issue (1): 13-16.DOI: 10.3696/j.issn.1672-6952.2011.01.004

• 石油化工 • 上一篇    下一篇

q-CS/TEOS复合膜的制备及吸附性能的研究

王 蕊,封瑞江* ,王吉林,敖 敏   

  1. 辽宁石油化工大学石油化工学院,辽宁抚顺113001
  • 收稿日期:2010-07-17 出版日期:2011-03-25 发布日期:2017-07-05
  • 作者简介:王蕊(1984-),女,辽宁沈阳市,在读硕士。

Preparation and Adsorption Performance of q-CS/TEOS Hybrid Membranes

 

WANG Rui, FENG Rui-jiang*, WANG Ji-lin, AO Min
  

  1. School of Petrochemical Technology, Liaoning Shihua University, Fushun Liaoning 113001, P.R.China
  • Received:2010-07-17 Published:2011-03-25 Online:2017-07-05

摘要: 以正硅酸乙酯为无机组分,季铵化壳聚糖为有机组分,通过溶胶-凝胶法制备一系列不同正硅酸乙
酯质量分数的季铵化壳聚糖/正硅酸乙酯(q-CS/TEOS)复合阴离子交换膜。利用红外光谱分析(FT-IR)对膜的
化学结构进行表征。另外,利用得到的杂化膜对水溶液中的Cr(Ⅵ)离子进行吸附性能考察。实验对吸附时间、体系
pH 值、溶液温度等因素对吸附性能的影响进行考察。结果表明,正硅酸乙酯质量分数为38%的杂化膜在吸附时间
180min、pH 值5.0~8.0、溶液温度35℃的条件下对Cr(Ⅵ)离子吸附性能较好。

关键词: 季铵化壳聚糖 ,  ,  , 正硅酸乙酯 ,  , 复合膜 ,  , Cr(Ⅵ) ,  ,  ,  ,  , 吸附

Abstract:  

A series of hybrid membranes composed of quaternized chitosan (q-CS) and tetraethoxysilane (TEOS) were prepared by sol-gel method,taking q-CS and the TEOS as organic and inorganic component respectively. The structure of the hybrid membranes was investigated by FT-IR. The adsorption performance of the membranes for Cr(Ⅵ) ions from aqueous solution was also studied. The effect of adsorption time, the pH value of solution and temperature of the adsorption on adsorption results were studied and show that the suitable membrane is composed of 38wt% TEOS, and the optimum adsorption conditions were carried out at 35 ℃ for 180 minutes with pH value of 5.0~8.0.

Key words: Quaternized chitosan  ,   , Tetraethoxysilane  ,   , Hybrid membrane  , Cr(Ⅵ) ,  , Adsorption

引用本文

王 蕊,封瑞江,王吉林,敖 敏. q-CS/TEOS复合膜的制备及吸附性能的研究[J]. 辽宁石油化工大学学报, 2011, 31(1): 13-16.

WANG Rui, FENG Rui-jiang, WANG Ji-lin, AO Min. Preparation and Adsorption Performance of q-CS/TEOS Hybrid Membranes[J]. Journal of Liaoning Petrochemical University, 2011, 31(1): 13-16.

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链接本文: http://journal.lnpu.edu.cn/CN/10.3696/j.issn.1672-6952.2011.01.004

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