硫酸亚铁／微波辐射稀酸水解玉米秸秆产生还原糖

辽宁石油化工大学学报 ›› 2012, Vol. 32 ›› Issue (4): 13-16.

硫酸亚铁／微波辐射稀酸水解玉米秸秆产生还原糖

张金辉，王硕，张起凯，李飞，杜云超

辽宁石油化工大学化学化工与环境学部，辽宁抚顺１１３００１

收稿日期:2012-05-28 出版日期:2012-12-20 发布日期:2017-07-06
作者简介:张金辉（１９６３－），男，辽宁大连市，教授，硕士

Hydrolysis of Corn Straw to Produce Reducing Sugar by Diluted Acid Over Ferrous Sulfate Under Microwave Radiation

ZHANG Jin-hui, WANG Shuo, ZHANG Qi-kai, LI Fei, DU Yun-chao

College of Chemistry, Chemical Engineering and Environmental Engineering,  Liaoning Shihua University, Fushun Liaoning 113001, P.R.China

Received:2012-05-28 Published:2012-12-20 Online:2017-07-06

摘要/Abstract

摘要： 　采用微波辐射，在金属盐硫酸亚铁为助催化剂的条件下，对玉米秸秆进行稀酸水解制备还原糖的研究，考察了硫酸亚铁质量分数、硫酸质量分数、液固质量比、微波辐射功率、微波辐射时间和微波辐射压力对水解制备还原糖产率的影响。结果表明，硫酸亚铁质量分数３％、硫酸质量分数２％、液固质量比１５、微波辐射功率１８７．５Ｗ、微波辐射时间３０ｍｉｎ、微波辐射压力０．３ＭＰａ为最佳水解条件，在此条件下还原糖产率可达３８．５％，与无金属盐时的微波辐射稀酸水解方法相比，还原糖产率增加了１．１倍，与无微波辐射时的稀酸水解方法相比，还原糖产率增加了２．８倍。

关键词: 　微波辐射 , 　水解 , 　玉米秸秆 , 　还原糖

Abstract: The corn straw was hydrolyzed by diluted acid via microwave radiation under the conditions of the metal salt ferrous sulfate as catalyst. The effect on the reducing sugar production rate was investigated by the concentration of ferrous sulfate, sulfuric acid content, ratio of liquid to solid, the microwave radiation power, time and pressure. The results show that the product yield can reach 38.5% under the best hydrolysis conditions: ferrous sulfate mass fraction of 3%, sulfuric acid mass fraction of 2%, mass ratio of liquid to solid 15, the microwave radiation power 187.5 W, the microwave radiation time 30 min and the microwave radiation pressure 0.3 MPa. Compared to the method without ferrous sulfate or without microwave radiation, this method shows higher yields by 1.1 and 2.8 times, respectively. 

Key words: 　Microwave radiation , Hydrolysis , Corn straw , Reducing sugar

张金辉，王　硕，张起凯，李　飞，杜云超. 硫酸亚铁／微波辐射稀酸水解玉米秸秆产生还原糖[J]. 辽宁石油化工大学学报, 2012, 32(4): 13-16.

ZHANG Jin-hui, WANG Shuo, ZHANG Qi-kai, LI Fei, DU Yun-chao. Hydrolysis of Corn Straw to Produce Reducing Sugar by Diluted Acid Over Ferrous Sulfate Under Microwave Radiation[J]. Journal of Liaoning Petrochemical University, 2012, 32(4): 13-16.

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