辽宁石油化工大学学报

辽宁石油化工大学学报 ›› 2017, Vol. 37 ›› Issue (2): 1-4.DOI: 10.3969/j.issn.1672-6952.2017.02.001

• 石油化工 • 上一篇    下一篇

聚苯胺插层三氧化钼复合光催化剂的制备及性能

郑 权1,房文超1,贾富智2,邱继一承1,杨占旭1,曾凡旭1   

  1. 1.辽宁石油化工大学 化学化工与环境学部,辽宁 抚顺 113001; 2.内蒙古金陶股份有限公司,内蒙 古赤峰 024327
  • 收稿日期:2016-09-28 修回日期:2016-11-04 出版日期:2017-04-20 发布日期:2017-05-04
  • 通讯作者: 杨占旭(1982-),男,博士,副教授,从事新型储能材料和催化材料的研究;E-mail:zhanxuy@126.com。
  • 作者简介:郑权(1995-),男,本科生,应用化学专业,从事新型储能材料方面的研究;E-mail:1652364669@qq.com。
  • 基金资助:
    国家自然科学基金项目(21401093);2015年省级大学生创新创业项目(201510148044)。

Preparation and Performance of Polyaniline Intercalated Molybdenum Trioxide Composites Photocatalysts

Zheng Quan,Fang Wenchao,et al   

  1. 1.CollegeofChemistry,ChemicalEngineeringandEnvironmentEngineering,LiaoningShihuaUniversity,Fushun  Liaoning 113001,China; 2.InnerMongoliaJintaoCorporationLimited,ChifengInnerMongolia024327,China
  • Received:2016-09-28 Revised:2016-11-04 Published:2017-04-20 Online:2017-05-04

摘要:         以苯胺柱撑的三氧化钼有机-无机杂化体为反应前躯体,在空气气氛下于120 ℃进行氧化聚合,制备了一种聚苯胺插层MoO3 复合材料。以罗丹明B(RhB)为目标降解物,以MoO3 复合材料为光催化剂,考察了其催化性能,并研究了光照时间、催化剂质量浓度和pH 与光催化降解效率的关系。结果表明,在pH 为1~4、催化剂的质量浓度为0.30~0.40g/L、光照时间2.0h的条件下,MoO3/PANI复合材料对罗丹明B具有良好的光降解效果,降解率最高可达98.00%。

关键词: 聚苯胺插层三氧化钼,    ,  罗丹明B,    ,  光催化,    ,  催化剂

Abstract:

       The aniline intercalated MoO3 organic-inorganic hybrid compound as precursor was prepared. Then it was treated as Oxidative polymerization in air atmosphere at 120 ℃, the polyaniline intercalated MoO3 composite was constructed. Rhodamine B (RhB) was used as the target degradation material, and the photocatalytic of MoO3 composite was investigated The effects of light time, catalyst dosage and pH value on photocatalytic degradation efficiency were studied. The results show that the MoO3/PANI composites have good photocatalytic degradation effect on Rhodamine B under the conditions of pH value of 1~4, catalyst mass concentration of 0.30~0.40 g/L and illumination time of 2.0 h, moreover that the highest degradation rate is up to 98.00%.

Key words: Polyaniline , intercalated   , MoO3   , composites,    , RhodamineB,    , Photocatalytic,    , Catalyst

引用本文

郑 权,房文超,贾富智,邱继一承,杨占旭,曾凡旭. 聚苯胺插层三氧化钼复合光催化剂的制备及性能[J]. 辽宁石油化工大学学报, 2017, 37(2): 1-4.

Zheng Quan,Fang Wenchao,et al. Preparation and Performance of Polyaniline Intercalated Molybdenum Trioxide Composites Photocatalysts[J]. Journal of Liaoning Petrochemical University, 2017, 37(2): 1-4.

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