Protected amino acid compounds are often widely used as intermediates of drug molecules and functional material intermediates. The high efficiency of Boc-protected amino acid esters provides an important prerequisite for their subsequent conversion in the entire process. Boc-tert-butyl phenylalanine was selected as the raw material, and the process of selectively removing the Boc protecting group while retaining the protecting group of tert-butyl ester to generate tert-butyl phenylalanine hydrochloride was studied. Under room temperature or low temperature conditions, the yield of about 82% can be achieved by deprotection under acidic conditions, and the reaction conditions are simple and mild, and the cost of process equipment is low, which realizes simple operation, economical benefits and environmental protection.

Using sodium lignosulfonate and copper chloride dihydrate as raw materials, and activated carbon modified materials under different synthetic conditions were prepared by calcination under N₂ atmosphere by impregnation and activation. The structure and surface morphology of the prepared materials were studied by X-ray diffraction (XRD), infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and other testing methods. Taking K₂Cr₂O₇ solution with mass concentration of 20 mg/L as the research object, the Cr(Ⅵ) content in the solution was detected by Diphenyl carbamide chromogenic method, and the adsorption capacity of the prepared activated carbon modified materials was calculated. According to the experimental results, when the proportion of copper is 20% and the calcination temperature is 700 ℃, the adsorption performance of the material is the best, and the adsorption capacity is 72.2 mg/g. The adsorption process conforms to the Langmuir monolayer adsorption and Pseudo-second-order kinetics.

The environmental contamination caused by tetracycline hydrochloride (TC) has aroused widespread concern, photocatalytic degradation of TC has become an effective method. CeO₂ was prepared by coprecipitation method, and solvothermal synthesis of CeO₂@UiO-66 composite catalysts. The prepared catalysts were characterized by FT-IR, XRD, SEM and EDS respectively, and the effects of the amount of CeO₂, catalyst mass concentration and H₂O₂ mass fraction on the photocatalytic degradation of TC were also investigated. The results showed that CeO₂@UiO?66 was successfully synthesized. When the amount of CeO₂ substance is 25 mmol, the mass concentration of TC solution is 20 mg/L, the mass concentration of catalyst is 0.2 g/L, and the mass fraction of H₂O₂ is 2%, CeO₂@UiO?66 photocatalytic effect is the best, and the TC degradation rate reaches over 98% when irradiated by UV lamp for 70 min. The free radical trapping experiments showed that holes and ·OH were the main contributors in the photocatalytic process. In addition, after six cycles, the degradation rate of TC composite photocatalyst can still maintain above 85%, which indicates its good stability.

Microbial dewaxing of crude oil is an efficient and simple method. In order to further improve the paraffin degradation rate of microorganisms, two strains L and K were used to form paraffin degradation mixed bacteria, and their degradation conditions were optimized. The factors affecting the degradation of mixed bacteria (culture temperature, initial pH value of culture medium, salt concentration, and V（L strain ）/V（K strain）) were determined by orthogonal experiment and single factor experiment. Box-Behnken method was used to design four?factor three?level experiment and response surface optimization, and a mathematical model was established to explore the best conditions for the degradation of paraffin by mixed bacteria. The experimental results showed that the influence of four single factors is as follows: V（L strain）/V（K strain）>culture temperature>salt concentration>initial pH value of culture medium. Their primary term, secondary term and individual interaction term had significant influence on the paraffin degradation rate. The optimal experimental operating conditions for the mixed bacteria to degrade paraffin were determined as follows: culture temperature 37.2 ℃, initial pH value of culture medium 7.3, salt concentration of culture medium 1.2%, ratio of mixed bacteria V（L strain）/V（K strain）=1.0∶1.6, and paraffin degradation rate 58.67%. The mixed bacteria were used to act on crude oil under the optimized conditions, and the biodegradation rate was 41.38%,have good application prospects.

Using the synergistic effect of surfactant mixture to reduce oil?water interfacial tension and crude oil viscosity is an important method to improve oil recovery in recent years.The content of each component of crude oil produced from each oil field is different, so it is necessary to screen the suitable surfactant according to the component content.In this paper, the interfacial tension and emulsifying properties of sodium dodecyl benzene sulfonate (SDBS) and lauryl glucoside (APG1214) in Liaohe crude oil were studied by rotating drop interfacial tensiometer and bottle test method. The interfacial tension was studied by changing different compounding ratios, salinity and pH value, and the viscosity of the emulsion was measured by viscometer.The results show that the interfacial tension between oil and water can be reduced and the stable heavy oil emulsion can be formed by adding proper amount of inorganic salt in combination of surfactant.

The effects of a single emulsifier octylphenol ethoxylate 10 (OP?10) and its compounding system on emulsion stability, rheology and the effect of organic bases on the interfacial tension were investigated. The results show that the optimal binary composition is as follows: The mass fraction of OP?10 is 1% and the mass fraction of sodium oleate (YSN) is 0.6%.The optimum compounding method can produce stable emulsion with thick oil, and the viscosity can be reduced from 1 168.22 mPa?s to 57.57 mPa?s, with the viscosity reduction rate of 91.03% and the water separation rate of 21.33%. The organobase triethanolamine (TEOA) can reduce the interfacial tension of the compounded system to the 10^-2 mN/m level.

Direct flame impingement heating technology is widely used in the field of steel heat treatment processes and is currently fueled by natural gas. Hydrogen, as a clean energy source and its high laminar flame propagation speed, combined with natural gas will improve the fuel combustion speed and reduce the emission of carbon oxides and nitrogen oxides. In this paper, a numerical model of direct flame impingement heating of steel plate was established using Fluent, and the heat transfer characteristics of direct flame impingement heating of steel strip were investigated under different hydrogen doping, Reynolds number, and factorless distance conditions. The results show that the temperature and heat flow density of the steel plate of the heated target decrease with the increase of hydrogen doping from 0 to 25% at a heating time of 10 s. The temperature of the steel plate stationary point decreases from 385.36 K to 374.31 K, and the heat flow density of the steel plate stationary point decreases from 154 828 W/m² to 137 926 W/m². With the increase of Reynolds number from 13 400 to 33 600, the steel plate stationary temperature increased from 347.04 K to 450.90 K, the pressure increased from 14.93 Pa to 136.53 Pa, but the uniformity of the temperature and pressure of the steel plate deteriorated gradually. The increase of the causeless distance from 25 to 45 made the temperature of the steel plate stationary point decreased from 442.42 K to 344.36 K, and the pressure was reduced from 106.00 Pa to 24.81 Pa and the distribution was more inhomogeneous.

Aerobic oxidative desulfurization is a safe and environmentally friendly desulfurization method, but oxygen usually needs to be activated under harsh conditions, the synthesis of efficient catalyst is an effective way to improve desulfurization activity. In this work, flower?like cobalt molybdate with large specific surface area was synthesized by one?step hydrothermal method using cobalt chloride and ammonium molybdate as raw materials. In addition, urea is used as precipitation agent and structure control agent. The morphology and structure of the CoMoO₄ were characterized by FT?IR, XRD, SEM, XPS and N₂ adsorption desorption techniques. Dibenzothiophene in simulated oil was removed using CoMoO₄ as catalyst and molecular oxygen as oxidant. The effects of reaction temperature, the flow of oxygen, the amount of CoMoO₄ and the type of sulfur compounds on the desulfurization rate were investigated. In addition, the recycling performance of flower?like CoMoO₄ was studied. The experiment shows that the desulfurization rate can reach 98.2% under the optimal reaction conditions. The catalyst can be reused for 5 times without significant reduction in oxidative desulfurization activity. The formation of superoxide radical in the oxidation desulfurization process resulting in high desulfurization activity.

A base?catalyzed 1,6?conjugate addition of p?QMs for the preparation of diaryl methyl ethers (thioether) has been developed with 37% to 95% yields, which realized the solvolysis reaction between p?QMs and alcohol (thiophenol) under the catalysis of 20% NaOH. The method features easy operation, mild condition and good functional tolerance. A gram scale experiment was examined in 80% yield, which provides possibility for potential application and transformation in later stage.

The hydrocracking unit is a Class A fire hazard device, which can be susceptible to fire and explosion accidents due to equipment failure. Therefore, it is essential to identify and quantitatively analyze the risk factors. In this paper, qualitative HAZOP, steady-state simulation, dynamic simulation and FTA are combined. Taking process flow of the absorbing-stabilizing system of an actual hydrocracking unit in a refining company as an example, and the quantitative risk analysis is carried out for the deviation of "high column pressure" of the absorption and desorption column and "high column temperature" of the naphtha stabilisation column. With the help of Aspen Plus software, the steady-state and dynamic simulation under dangerous conditions is carried out, and the probability of the consequences of the dangerous accident is calculated by FTA method. The results show that this method can help experts understand the propagation process of the accident, master the safety response time of the personnel, which is conducive to the prevention and timely treatment of accidents, and effectively improve the intrinsic safety level of the hydrocracking units.

Gasoline molecular blending technology on?line requires rapid access to detailed molecular composition information of various types of component oils. In this paper, an autoencoder?based method for the rapid resolution of gasoline molecular composition is developed, which can directly predict the detailed monomeric hydrocarbon composition of gasoline from near?infrared spectra. The constructed autoencoder model of gasoline molecular composition can explore the potential features and recover the original molecular composition by decoding the potential features. The artificial neural network algorithm is used to correlate the NIR spectral information with the potential features of gasoline composition. The accuracy of the model is verified by using hydrogenated gasoline with the average absolute error is 0.033. The model developed in this work applies the current popular autoencoder algorithm to the traditional petrochemical process, which is an important guideline for blending online and real?time optimization of gasoline molecules.

Pollution caused by petroleum?based plastic products has become a problem that is difficult for human beings to solve, and the existing treatment methods are both energy?consuming and easy to cause secondary pollution. The study found that the bacteria that degrade plastic in the intestines of Galleria mellonella (Lepidoptera: Pyralidae) larvae can effectively accelerate the degradation of plastics. This experiment uses polystyrene (PS) packaging boxes, which are common in life, as the only food source to feed the larvae of the large wax borer, enriching the PS?degrading bacteria in the intestines of the G. mellonella larvae. After dissection, culture, and isolation, four strains were obtained: PD?1, PD?2, PD?3 and PD?4. The degradation capacity of MSM culture medium with PS film as the only carbon source was inoculated with each strain, and the degradation rate of PD?1 on PS film was the highest, which was 1.8%. PD?1 was observed by strain morphology, physiological biochemical determination and phylogenetic tree construction, and it was identified as Enterobacter colebella (Klebsiella). Meanwhile, the method of UV and nitric acid pretreatment of PS film were used to improve the degradation rate of the strain, and the results showed that the weight loss rate of PD?1 degradation of nitric acid?treated PS film was improved, which was 2.5%, while the UV group was 0.8%, indicating that PS film was more easily degraded by PD?1 after nitric acid treatment.

ZnO has a strong UV absorption capacity, but also has a high photocatalytic performance, which limits its application in the field of UV shielding. In order to explore the possibility of ZnO's application in the field of ultraviolet shielding, this article uses VASP to construct a ZnO/CeO₂ heterojunction and performs electronic and optical simulation calculations on it. Then lignin is used to combine with the synthesized ZnO/CeO₂ heterojunction to prepare lignin-modified nano-ZnO/CeO₂ heterojunction. Through the FT-IR, XRD, SEM, UV-Vis-DRS means the characterization of samples. The UV shielding properties of the synthesized samples were investigated with methylene blue as the protection object. The results show that the light absorption performance of the samples at 280～420 nm is better than that of ZnO/CeO₂ samples. The retention rate of methylene blue for 70 min under UV irradiation was 77.92%, indicating that the synthesized sample was a UV shielding material with high UV shielding properties and low photocatalytic activity.

The direct method was used to prepare polyurea lubricating grease, and the effects of several different types of additives on the extreme pressure and anti?wear performance for polyurea lubricating grease were investigated and studied. The results demonstrate that several types of additives have good compatibility with polyurea grease, and they have little undesirable influence on colloidal stability of polyurea grease, and they can also enhance thermal stability of polyurea grease. Moreover, the addition of additives can significantly improve the performance of extreme pressure and wear resistance for polyurea lubricating grease. And in the experiments, it was found that the composite multifunctional additive containing sulfur and phosphorus has a relatively better effect on improving the extreme pressure and wear resistance of polyurea lubricating grease. The research results can provide a reference basis for the improvement of extreme pressure and anti?wear property for polyurea lubricating grease, achieving a relatively optimized comprehensive performance, thereby enhancing its practical utilization performance under the harsh working conditions for high load and high speed mechanical equipment.

Polylactic acid/Poly(butylene adipate?co?terephthalate)/Poly(methyl methacrylate)?b?poly (butyl acrylate)?b?poly (methyl methacrylate)ternary blends (PLA/PBAT/MAM) were prepared by melt blending, and the effect of MAM relative molecular weight on the morphology, structure and properties of the blends was investigated. The results showed that the addition of MAM block copolymer can inhibits the crystallization of PLA，improve the compatibility of PLA/PBAT, reduce the particle size of the dispersed phase and make the distribution more uniform, improve the impact properties and elongation at break of the blends. And the relative molecular weight of MAM increased, the impact strength and elongation at break of the blend increased, the smaller the size of the dispersed phase particles, and the more uniform of particle size distribution.

Coumarins are a key class of heterocyclic lactone compounds, which have good biological activity. 3?sulfonyl coumarin derivatives were prepared by visible light promoted reaction of benzoalkynyl esters with sodium benzenesulfonate, and their reaction mechanism was studied. The results showed that under mild reaction conditions, 3?sulfonyl coumarin derivatives can be synthesized with moderate to good yields using sodium benzenesulfite as the precursor of sulfonyl radicals and persulfate as the oxidant through a cascade radical addition cyclization strategy, providing a concise, green, and efficient synthetic route for the preparation of functionalized coumarin derivatives.

Two adsorbents, magnesium aluminum calcined hydrotalcite (MgAl LDO) and magnesium aluminum iron calcined hydrotalcite (MgAlFe LDO), were synthesized by coprecipitation method, and characterized by X?ray powder diffraction (XRD) analysis, scanning electron microscopy (SEM) analysis, Fourier transform infrared spectroscopy (FT?IR) analysis and BET specific surface area test analysis, etc. The adsorption performance of the two adsorbents for fluoride in wastewater was also studied. The effects of the ratio of metal substances, calcination temperature, initial mass concentration of F^-, and adsorbent dosage on the removal efficiency of fluoride in wastewater were investigated. The results showed that MgAlFe LDO had a uniform pore structure distribution, a large specific surface area, and a higher adsorption capacity for fluoride in wastewater than that of MgAl LDO. When n (Mg²⁺)/n (Al³⁺)/n (Fe³⁺)=3.0∶0.6∶0.4, the initial mass concentration of F^- was 20 mg/L, the calcination temperature was 300 ℃, and the dosage of MgAlFe LDO was 0.4 g, the removal effect of fluoride in wastewater was optimal. After 2 hours of reaction, the removal rate of fluoride in the wastewater was 98.35%.

ZSM?5 has been widely used in the field of petrochemical industry. The extensive use of organic templates in its conventional synthesis process has caused serious problems on environmental and cost. In this paper, the hydrothermal synthesis of ZSM?5 with tetraethyl orthosilicate, aluminum sulfate octadecahydrate and alkaline hydrolysis product of HZSM?5 as silica source, alumina source and structural directing agent, respectively, has been investigated, which aims at developing of new process for green synthesis of zeolites. The synthesized samples were characterized by a series of techniques, such as XRD, TEM, SEM, N₂ physical adsorption and TG analysis. It has been shown that successful synthesis of ZSM?5 can be achieved by induction of alkaline hydrolysis product of HZSM?5 in organic template?free system. The prepared sample possesses a relative low crystallinity and specific surface area than ones from conventional process. The study in this paper has provided the chance for combination of green synthesis of zeolites and post?treatment route for synthesis of hierarchical zeolites.

The influence of curing temperature on catalytic desulfurization, nitrogen and acid removal of NiW/Al₂O₃ hydrotreating catalyst during the curing tprocess was studied. The catalyst with incomplete curing was re?cured and its hydrogenation performance was studied. The structure of the vulcanized catalyst was characterized by physical adsorption (BET), X?ray diffraction (XRD) and X?ray photoelectron spectroscopy (XPS). The results showed that the sulfur content and degree of vulcanization on the catalyst increased with the increase of vulcanization temperature, and the carbon accumulation also increased, which led to the decrease of the specific surface area, pore volume and average pore size of the catalyst. After vulcanization, the active phase of the catalyst changed from low active W⁶⁺ and Ni²⁺ to high active W⁴⁺ and Ni-W-S phases. After revulcanization, the pore volume and average pore size of the catalyst decreased, while the specific surface area, sulfur and carbon contents increased. The increase in carbon deposition covered part of the active center and reduced the atomic ratio of W and Al on the catalyst surface, resulting in the aggregation of active metals in the vulcanized state and reduced the activity of the catalyst, indicating that the revulcanized catalyst was difficult to achieve complete vulcanized catalyst activity.

In the process of oil exploitation, processing, storage and transportation, the total petroleum hydrocarbon (TPH) released into the soil not only changes the physical and chemical properties of the soil, but also seriously affects the quality of the water environment through the process of migration and transformation. Addressing the environmental issue of petroleum?contaminated soils, the development of efficient, green, and environmentally friendly remediation technologies has become a critical need in the industry. This paper reviews the main remediation technologies for petroleum?contaminated soils based on current domestic and international research. The study showed that physical methods are suitable for remediating soils contaminated with highly volatile and highly permeable petroleum, chemical methods are appropriate for treating severely and recalcitrantly contaminated soils, and biological methods are more environmentally friendly and better suited for treating mildly contaminated soils. By comparing the principles and application ranges of different remediation technologies, it is evident that combined remediation technologies offer strong versatility and widespread applicability. This paper also explores future trends in the development of green and environmentally friendly remediation technologies for petroleum?contaminated soils, aiming to provide a reference for practical applications in soil remediation.

The pollution of tetracycline antibiotics in the water environment is increasingly serious, and the effective removal of residual antibiotics in water is an urgent problem to be solved. The co?precipitation method was used to prepare Cu?Al layered double hydroxides biochar composites (CuAl?LDH@BC) intending to remove tetracycline hydrochloride (TCH) from water. The physicochemical properties of the CuAl?LDH@BC surface were analyzed by SEM, XRD, and FTIR, and the adsorption performance of the tetracycline hydrochloride solution was revealed. The experimental results show that the adsorption process is more consistent with the quasi?second?order kinetic model and Langmuir model, and the maximum adsorption capacity of TCH is 78.68 mg/g at 298 K, and the neutral condition CuAl?LDH@BC has the best removal effect on TCH, which has strong anti?interference ability in water environment. The mechanisms involved in the adsorption of TCH by CuAl?LDH@BC may include hydrogen bonding, surface complexation, π-π interaction, and electrostatic interaction. The results show that Cu?Al layered double hydroxides and biochar composites, as low?cost and high?efficiency adsorbents, have a broad application prospect in the adsorption of tetracycline antibiotics in water.

Aromatic?based green rubber filler oil is prepared from furfural extraction oil of a petrochemical company by using compound solvents for secondary extraction to separate polycyclic aromatic hydrocarbons present in the oil. Three composite solvents are used for comparison, and the effects of operating conditions, such as extraction temperature and agent?oil mass ratio, on the yield and PCA mass fraction of the refined oil are investigated. A detailed compositional analysis is conducted using the alumina adsorption column method and infrared spectroscopy. The experimental results demonstrate that the optimal operating conditions are primary solvent extraction at 70 ℃ and an agent?oil mass ratio of 5∶1, and secondary solvent extraction at 50 ℃ and an agent?oil mass ratio of 2∶1. The yield of refined oil is 32.34%, the mass fraction of PCA is 2.98%, and the aromatic carbon ratio is 18.65%. These results meet the requirements outlined in EU Directive 2005/69/EC. The results demonstrate that the composite solvent significantly enhances the selectivity and solubility of the solvent, effectively removes PAHs from the oil, and ensures a high product yield and aromatic carbon ratio.

In order to solve the problems of poor blood compatibility and low adsorption capacity of chitosan (CS) when using graphene oxide (GO) alone, a graphene oxide/chitosan blend membrane (GO/CS membrane) was prepared. Microscopic morphology and composition analysis were conducted using SEM and FTIR, and bilirubin adsorption experiments were carried out on GO/CS membranes. The results showed that when the mass fraction of GO in the casting solution was 3%, the adsorption capacity of GO/CS membrane for bilirubin was optimal. The absorption intensity of C=O belonging to the amide group increases near 1 650 cm^-1, while the stretching vibration peak of -NH₂ at 3 353 cm^-1 and the bending vibration peak of N-H at 1 570 cm^-1 weaken simultaneously. Additionally, there is no stretching vibration peak of carboxyl group C=O near 718 cm^-1, indicating that an amide reaction has occurred between GO and CS molecules, and the GO/CS membrane has been successfully prepared. Under the conditions of a reaction temperature of 37 ℃ and an adsorption time of 120 min, the GO/CS membrane exhibits the best bilirubin adsorption effect, with a saturated adsorption capacity of 77.8 mg/g. Increasing the mass concentration of bilirubin and lowering the pH under alkaline conditions are both beneficial for adsorption. Increasing the ionic strength of the solution or the mass concentration of bovine serum albumin is not conducive to the adsorption of bilirubin.

Based on the background of 'dual carbon' , the chemical chain hydrogen production process is a novel alternative to traditional hydrogen production schemes, with economic and efficient characteristics. Choosing appropriate oxygen carriers is crucial for the stability of the process, as they require high reactivity, selectivity, material strength, and sintering resistance. This article provides an overview of commonly used chemical chain processes, including dual reactors and triple reactors, and compares the performance of several different metal oxygen carriers in depth. At the same time, summarizing the reaction mechanisms of different oxygen carriers is helpful for selecting appropriate oxygen carriers in the process. Due to the phenomenon of coking and agglomeration of oxygen carriers during the reaction process, numerous researchers have paid significant attention to its avoidance at the micro level. Finally, the prospects of the oxygen carrier used as a renewable, sustainable and environmentally friendly material are prospected.

Thiacalix[4]arene ligands have the advantages of high recognition, derivatization, excellent stability and other advantages. Lanthanide (Ln) ions can coordinate with thiacalix[4]arene ligands to form multi?functional coordination clusters, which received increasing attention due to their unique catalytic, magnetic, optical properties. Thiacalix[4]arene can sensitize Ln ions to luminescence by the coordination of phenol and S groups via the "Antenna effect". This paper reviewed recent advances in structures, luminescent properties, and applications of luminescent Ln?thiacalix[4]arene complexes.

Biochar with developed pore structure was prepared by using high?humidity Chinese herbal medicine wastes (CHMWs) as raw material, using the water vapor generated by its own water under a high temperature environment for physical activation，and the effects of moisture content, activation temperature and activation time on the performance of biochar were investigated. The performance of biochar was analyzed by physical adsorption instrument, Fourier transform infrared spectroscopy, scanning electron microscopy and other instruments, and the optimal reaction conditions for biochar preparation were obtained, and the activation mechanism of biochar prepared from CHMWs was discussed. The prepared biochar was used to adsorb wastewater containing Cd²⁺ and Cu²⁺, and the adsorption kinetics were discussed. The experimental results showed that under the conditions of 700 ℃ heating temperature, 60 min heating time and 50% moisture content of the CHMWs, the biochar with a specific surface area of 309.29 m²/g and a pore volume of 0.116 8 cm³/g and was obtained. The experimental results of adsorption showed that the adsorption kinetics on Cu²⁺and Cd²⁺ conformed to the quasi second order kinetic equation, and the optimal adsorption capacities of Cu²⁺ and Cd²⁺ were 20.66 mg/g and 17.41 mg/g respectively.

A novel adsorption material of bimetallic Cu and Ni?doped TiO₂?modified carbon nanotubes was prepared by sol?gel methodmethod,and experiments on simultaneous desulfurization and denitrification were carried out.The effects of O₂ volume fraction,H₂O volume fraction and volume airspeed on desulfurization and denitrification were studied,Under the condition of a molar ratio of Cu to Ni of 2.The results showed that the adsorption capacity of MWCNTs/Cu?Ni?TiO₂ was significantly better than that of single?metal modified materials. Under the condition of simulating flue gas, the adsorption effect of the bimetallic modified material was the best when the mass concentration of SO₂ was 3 140 mg/m³, the mass concentration of NO was 736 mg/m³, the volume fraction of water vapor was 5%, the fraction of O₂ was 8%, and the volume space velocity was 2 598 h^-1. The optimal adsorption amount of SO₂ was 20.43 mg/g, and the optimal adsorption amount of NO was 0.86 mg/g.

In order to improve the success rate of high temperature and complex formation structural oil wells, the preparative temperature sensitive self?consolidation resin is used to modify the surface of the aggregate material, and the thermally consolidated rigid plug material is obtained, then auxiliaries are chosen to build a novel bridge sealing and thermal consolidation plugging system that could resist temperature to 190 ℃. Infrared spectroscopy, thermal analysis, scanning electron microscopy were employed to study the molecular structure, microstructure and thermal stability of the resin, thermally consolidated rigid plug material and the plugging system, the suspension stability, consolidation rate, consolidation strength and permeability of the plugging system were also investigated. The results show that the constructed plugging system has the advantages of good suspension stability and wide solidification time window in bentonite slurry with mass fraction of 5%, and the compressive strength of the solidified body after curing at 90~190 ℃ are all over 6 MPa; at the same time, the water phase permeability of the solidified body cured at 190 ℃ is 6.32×10³ μm² under the driving pressure of 12 MPa, and the plugging rate is more than 98.00%. It is expected to meet the plugging requirements of high?temperature formation.

Electrospinning can regulate fiber and membrane structures at the nanoscale, and doping graphene futher enhances the electrochemical function of nanofilms. Starting from the structure of graphene, we optimize the relationship between graphene doping ratio and nanofiber size and study the effects of electrospinning voltage, feed rate, spinning distance and time on membrane structure and electrochemical performance. Research has shown that when the graphene doping mass fraction in the nanofilm is 7%, the voltage is 24 kV, the spinning distance is 15 cm, the feed rate is 0.01 mL/min, and the time is 2 h, the diameter of the fibers in the nanofilm structure is 0.162 μm, and the impedance is 220.8 Ω. Under electrospinning conditions, the doping of graphene can control the preparation of nano films and optimize their electrochemical properties in multiple ways.

A novel ruthenium(Ⅱ)?catalyzed C-H/C-N annulation of 1?phenyl?2?pyrazolin?5?one with ethylene carbonate was designed. In this transformation, the vinylene carbonate acts as an ethynol or alkyne surrogate without any external oxidant as well as bases involved. The reaction exhibits a broad substrate scope with excellent functional group compatibility, affording a series of 1H?pyrazolo[1,2?a]cinnolin?1?ones in 42%~87% yields. A possible mechanism involving a sequential C-H activation/intramolecular C-N bond formation/ CO₂ or CO {}_{\mathrm{3}}^{\mathrm{2}-} elimination is proposed. In addition, the reaction can also be carried out on a gram scale with satisfactory yield.

The quaternary ammonium group (QA) commonly used in conventional anion exchange membranes (AEMs) has a low dissociation constant with OH^-, resulting in poor conductivity. The crown ether group can significantly enhance the ion exchange capacity (IEC) and OH^- conduction efficiency of AEMs due to its ability to form positively charged complexes with alkali metal cations. Meanwhile, the ether bond in the crown ether ring exhibits good alkali and chemical stability. In view of the above advantages, a series of AEMs grafted with bi?crown ethers were successfully prepared by grafting dibenzo?18?crown?6?ether?modified polyvinyl alcohol (PVA) via metastable acid. The results showed that the bi?crown ether anion?exchange membranes exhibited higher OH^-selectivity and chemical stability compared with the mono?crown ether membrane materials; the prepared AEMs exhibited good OH^- selectivity and chemical stability in terms of electrical conductivity (conductivity of 165.5 mS/cm at 80 ℃), mechanical properties (tensile strength of 47 MPa at room temperature), and alkali stability (only 4.52% decrease in conductivity after immersion in KOH at a concentration of 6 mol/L for 168 h), and the high efficiency electrolysis of water to produce hydrogen based on platinum charcoal as the anode material, and the efficiency of electrolytic reduction reached 80%.