石油化工高等学校学报

石油化工高等学校学报 ›› 2007, Vol. 20 ›› Issue (4): 28-32.

• 石油化工 • 上一篇    下一篇

TiO2/钛酸钾晶须光催化剂的制备及其性能研究

李松田1,2, 闫永胜1, 吴春笃*1* , 霍鹏伟1, 储金宇1   

  1. 1.江苏大学环境学院,江苏镇江212013; 2.平顶山学院化学化工学院,河南平顶山467000
  • 收稿日期:2006-12-29 出版日期:2007-12-20 发布日期:2017-06-28
  • 作者简介:李松田(1963-),男,河南叶县,教授,博士。
  • 基金资助:
    江苏省研究生科研创新计划(CX07B-175z);河
    南省自然科学基金项目(0624720029)

Preparation and Performances of TiO2 /Potassium Titanate Photocatalyst

LI Song-tian1,2YAN Yong-sheng1WU Chun-du*1*HUO Peng-wei1CHU Jin-yu1   

  1.  
    1. School of Environment, Jiangsu University, Zhenjiang Jiangsu 212013,P.R. China;
    2. School of Chemistry and Chemcial Engineering, Pingdingshan University, Pingdingshan Henan 467000,P.R. China
  • Received:2006-12-29 Published:2007-12-20 Online:2017-06-28

摘要: 为考察光催化技术对有机污染物的降解作用,选择了一种新的催化剂载体,采用溶胶-凝胶法制备
了TiO 2/钛酸钾晶须光催化剂。通过X-射线衍射、扫描电镜对产品进行了表征。EDS图谱显示,钛酸钾晶须的能
谱峰以Ti,O,K为主,而包覆后则以Ti,O 为主,K的谱峰已消失,说明晶须表面已被包覆上TiO 2。XRD图谱中出
现了与锐钛型TiO 2 的特征峰相吻合的衍射峰。在光化学反应器中,以中压汞灯为光源,罗丹明B为底物,研究了
TiO 2/钛酸钾的光催化性能。TiO 2/钛酸钾催化剂对罗丹明B的脱色作用受pH 值、光照强度、反应温度、曝气量、催
化剂用量等因素的影响。当罗丹明B 质量浓度为8 mg/L 时,加入0.01g/L 的TiO 2/钛酸钾,在160 min之内,
TiO 2/钛酸钾对罗丹明B的脱色率达到95%以上,比TiO 2 单独处理提高了0.50~1.91倍。

关键词: TiO2/钛酸钾 ,   , 光催化  ,   , 罗丹明B    ,  ,  催化剂载体

Abstract: In order to investigate the decomposition function of photocatalytic technique to the organic contamination, a new carrier of catalyst was chosen. Sol-gel method was used to preparate TiO2/potassium titanate photocatalyst. X-ray diffraction and SEM were used to token the product.   EDS shows that the main peak included Ti, O, K in potassium titanate whisker. The main peak of K disappeared and the peaks of Ti, O stayed after whisker was covered. It indicates that the surface of sample is covered by TiO2. XRD shows that diffraction peak appeared, which is corresponded to the peak of anatase TiO2. In the reaction device of photochemistry, using middle-pressure mercury lamp as illumination, rhodamine B as simulant pollutant, the photocatalytic performance of TiO2/potassium titanate was studied. The decoloration rate of TiO2/potassium titanate which was used to deal with rhodamine B in the experiment was influenced by the pH value, light intensity, reaction temperature, aeration amount, the dosage of catalyst etc. When the concentration of rhodamine B was 8 mg/L, the dosage of TiO2/potassium titanate was 0.01 g/L. The decoloration rate of TiO2/potassium titanate dealt with the rhodamine B reach over 95% in 160 minutes, and compared with TiO2, the decoloration rate of rhodamine B was improved 0.50~1.91 multiple.

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引用本文

李松田, 闫永胜, 吴春笃*,霍鹏伟, 储金宇. TiO2/钛酸钾晶须光催化剂的制备及其性能研究[J]. 石油化工高等学校学报, 2007, 20(4): 28-32.

LI Song-tian,YAN Yong-sheng,WU Chun-du*,HUO Peng-wei,CHU Jin-yu. Preparation and Performances of TiO2 /Potassium Titanate Photocatalyst[J]. Journal of Petrochemical Universities, 2007, 20(4): 28-32.

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