石油化工高等学校学报

石油化工高等学校学报 ›› 2014, Vol. 27 ›› Issue (2): 10-14.DOI: 10.3969/j.issn.1006-396X.2014.02.003

• 石油化工 • 上一篇    下一篇

溶聚丁苯橡胶接枝 MAH的性能研究

杨金娟1,2，栗晓杰1,2，林青峰1，陈力军3，杨明山1，刘冰1,2，戴玉华1   

  1. ( 1. 北京石油化工学院材料科学与工程学院特种弹性体复合材料北京市重点实验室, 北京1 0 2 6 1 7;2. 北京化工大学材料科学与工程学院, 北京1 0 0 0 2 9; 3. 中国石化北京燕山分公司合成橡胶一厂, 北京1 0 2 5 0 0)
  • 收稿日期:2013-12-17 修回日期:2014-03-18 出版日期:2014-04-25 发布日期:2014-06-16
  • 通讯作者: 戴玉华( 1 9 7 1 - ) 女, 博士, 副教授, 从事高分子功能材料方面的研究; E - m a i l : d a i y u h u a@b i p t . e d u. c n。
  • 作者简介:杨金娟( 1 9 8 7 - ) , 女, 硕士研究生, 从事橡胶改性方面的研究; E - m a i l : y a n g j i n j u a n@b i p t . e d u. c n。
  • 基金资助:
    2 0 1 3年北京市本科生科学研究计划项目( 2 0 1 3 J 0 0 0 6 3) 。

Properties of SSBR Grafted with Maleic Anhydride

  1. (1. Beijing Key Lab of Special Elastomers and Composites, College of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China; 2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China;  3.Synthetic Rubber Plant of Beijing Yanshan Petrochemical Co., Ltd., SINOPEC, Beijing 102500,China)
  • Received:2013-12-17 Revised:2014-03-18 Published:2014-04-25 Online:2014-06-16

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摘要： 溶聚丁苯橡胶( S S B R) 由于其优良的耐磨、 耐低温等性能, 主要用于轮胎的胎面、 胎体和胎侧等部位,但由于S S B R是一种非极性橡胶, 使得它与白炭黑等极性填料的结合力较弱。为了提高S S B R与白炭黑的相容性,以马来酸酐( MAH) 为极性单体对S S B R进行接枝改性。研究了接枝聚合物( S S B R - g - MAH) 与白炭黑共混后的胶料的各项性能, 探讨了接枝率对胶料性能的影响。结果表明, 溶聚丁苯橡胶接枝了 MAH 后, 接触角降低, 门尼黏度增大, 硫化时间延长, 胶料的综合力学性能有不同程度的提高。动态力学( DTMA) 测试表明, 接枝 MAH 后实现了胶料抗湿滑性能的提高和滚动阻力的降低, 为轮胎胎面胶提供了理想的材料。

关键词: 溶聚丁苯橡胶,    ,  , 马来酸酐,    ,  , 白炭黑

Abstract: Solutionpolymerized styrenebutadiene rubber (SSBR) was mainly used in tire, such as tread, carcass and sidewall, because of its excellent abrasion resistance and low temperature performance. But compatibility between SSBR with SiO2 is poor due to its nonpolar . In order to improve compatibility between SSBR with SiO2, series of modified SSBR were prepared by grafting with maleic anhydride (MAH) as graft monomer. The properties of composites composed by SSBR and SiO2 were studied and influence of grafting yield of SSBRgMAH was also investigated. The results showed that the contact angle of SSBRgMAH was decreased, the Mooney viscosity was increased after grafted with MAH and the mechanical properties of rubber was improved when curing time was extended. Dynamic mechanical testing showed that wet skid resistance of vulcanizates was improved and rolling resistance reduced, which will be an ideal material for tire tread.

Key words: Solutionpolymerized styrenebutadiene rubber,    ,  Maleic anhydride,    ,  Silicon dioxide

引用本文

杨金娟, 栗晓杰, 林青峰. 溶聚丁苯橡胶接枝 MAH的性能研究[J]. 石油化工高等学校学报, 2014, 27(2): 10-14.

Yang Jinjuan,Li Xiaojie,Lin Qingfeng,et al. Properties of SSBR Grafted with Maleic Anhydride[J]. Journal of Petrochemical Universities, 2014, 27(2): 10-14.

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