石油化工高等学校学报

石油化工高等学校学报 ›› 2023, Vol. 36 ›› Issue (2): 63-69.DOI: 10.12422/j.issn.1006-396X.2023.02.008

• 催化剂及催化材料 • 上一篇    下一篇

水热时间对CuO/CeO2催化甲醇水蒸气重整制氢的影响

杨昕毓1(), 孙舒2, 石岩3, 冯旭1, 韩蛟1, 张财顺1, 张磊1(), 高志贤1   

  1. 1.辽宁石油化工大学 石油化工学院,辽宁 抚顺 113001
    2.天津保泰安全技术服务有限公司,天津 300457
    3.中国石油抚顺石化公司 营销调运部,辽宁 抚顺 113000
  • 收稿日期:2022-10-03 修回日期:2022-10-26 出版日期:2023-04-25 发布日期:2023-05-06
  • 通讯作者: 张磊
  • 作者简介:杨昕毓(1996⁃),女,硕士研究生,从事催化新材料方面的研究; E⁃mail:yxy960321@163.com
  • 基金资助:
    国家自然科学基金项目(21673270);辽宁省教育厅科学研究经费项目(L2019012)

Effects of Hydrothermal Reaction Time on the Performance of CuO/CeO2 Catalyst for Hydrogen Production from Steam Reforming Methanol

Xinyu Yang1(), Shu Sun2, Yan Shi3, Xu Feng1, Jiao Han1, Caishun Zhang1, Lei Zhang1(), Zhixian Gao1   

  1. 1.School of Petrochemical Engineering,Liaoning Petrochemical University,Fushun Liaoning 113001,China
    2.Tianjin Baotai Security Technology Services Ltd. ,Tianjin 300457,China
    3.Marketing and Transportation Department,CNPC Fushun Petrochemical Company,Fushun Liaoning 113000,China
  • Received:2022-10-03 Revised:2022-10-26 Published:2023-04-25 Online:2023-05-06
  • Contact: Lei Zhang

摘要:

以六水合硝酸铈和尿素为原料,通过改变水热时间制备了CeO2?XX为水热时间,X=3、6、12、24 h)载体,对其进行等体积浸渍法负载活性组分Cu获得CuO/CeO2?X催化剂,将其应用于甲醇水蒸气重整制氢(MSR)反应中。通过XRD、BET、H2?TPR等表征手段,探索水热时间对CeO2?X载体、CuO/CeO2?X催化剂的结构和物化性质的影响,并考察了CuO/CeO2?X催化剂在MSR反应中的催化性能。结果表明,CuO/CeO2?6催化剂在MSR反应中展现出较好的催化活性;在反应温度为280 ℃、水醇物质的量比为1.2、甲醇气体体积空速(GHSV)为800 h-1的条件下,甲醇转化率可达92.8%。

关键词: 水热法, Cu?Ce催化剂, 甲醇水蒸气重整, 氧化铈, 氢气

Abstract:

CeO2?X (X is the hydrothermal synthesis time, X=3, 6, 12, 24 h) carriers were prepared by varying the hydrothermal synthesis time using Ce(NO3)3·6H2O and urea as raw materials, and CuO/CeO2?X catalysts were obtained by isovolumetric impregnation with active component Cu, which were applied to methanol steam reforming (MSR) reaction. The effects of hydrothermal synthesis time on the structure and physicochemical properties of the prepared CeO2?X carriers and CuO/CeO2?X catalysts were explored by XRD, BET, H2?TPR.The performances of the CuO/CeO2?X catalyst samples were evaluated in methanol steam reforming(MSR) reaction.The results show that the CuO/CeO2?6 has good catalytic activity. At the reaction temperature of 280 °C, when the molar ratio of water to methanol was 1.2, and the space velocity of methanol vapor (GHSV) was 800 h-1, the methanol conversion rate could reach 92.8%.

Key words: Hydrothermal method, Cu?Ce catalyst, Methanol steam reforming, Cerium oxide, Hydrogen

中图分类号: 

引用本文

杨昕毓, 孙舒, 石岩, 冯旭, 韩蛟, 张财顺, 张磊, 高志贤. 水热时间对CuO/CeO2催化甲醇水蒸气重整制氢的影响[J]. 石油化工高等学校学报, 2023, 36(2): 63-69.

Xinyu Yang, Shu Sun, Yan Shi, Xu Feng, Jiao Han, Caishun Zhang, Lei Zhang, Zhixian Gao. Effects of Hydrothermal Reaction Time on the Performance of CuO/CeO2 Catalyst for Hydrogen Production from Steam Reforming Methanol[J]. Journal of Petrochemical Universities, 2023, 36(2): 63-69.

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