导电高分子基柔性应变传感材料研究进展

doi:10.3969/j.issn.1672-6952.2022.02.007

辽宁石油化工大学学报 ›› 2022, Vol. 42 ›› Issue (2): 44-49.DOI: 10.3969/j.issn.1672-6952.2022.02.007

导电高分子基柔性应变传感材料研究进展

李华¹(), 朱雨田², 赵桂艳¹()

^1.辽宁石油化工大学石油化工学院，辽宁抚顺 113001
^2.杭州师范大学材料与化学化工学院，浙江杭州 311121

收稿日期:2021-03-15 修回日期:2021-04-01 出版日期:2022-04-25 发布日期:2022-05-21
通讯作者: 赵桂艳
作者简介:李华（1994⁃），男，硕士研究生，从事导电高分子传感材料研究；E⁃mail：1573488610@qq.com。
基金资助:
辽宁省教育厅科研基金项目(L2019013);辽宁石油化工大学引进人才科研启动基金项目(2016XJJ?001)

Research Progress of Conductive Polymer Flexible Strain Sensing Materials

Hua Li¹(), Yutian Zhu², Guiyan Zhao¹()

^1.School of Petrochemical Engineering，Liaoning Petrochemical University，Fushun Liaoning 113001，China
^2.College of Materials，Chemistry and Chemical Engineering，Hangzhou Normal University，Hangzhou Zhejiang 311121，China

Received:2021-03-15 Revised:2021-04-01 Published:2022-04-25 Online:2022-05-21
Contact: Guiyan Zhao

摘要/Abstract

摘要：

随着人机交互、电子皮肤、可穿戴电子等新兴领域的迅速发展，作为核心部件之一的柔性应变传感材料成为人们关注的热点。由导电材料与柔性高分子复合而成的导电高分子基复合材料具有柔韧性好、质轻、易加工成型等优势，且材料导电性能在应变刺激下发生改变，因此可用作柔性应变传感材料。综述了基于导电高分子复合材料的柔性应变传感材料的分类及特点，详细介绍了该类传感材料的应变响应机理，并总结了影响导电高分子复合材料应变传感性能的因素。

关键词: 导电高分子复合材料, 柔性应变传感材料, 传感机理, 应变传感性能

Abstract:

With the rapid development of human?computer interaction, electronic skin, wearable electronics and other emerging fields, flexible strain sensing materials as one of the core components have become the hot spot of the current research. The conductive polymer composites composed of conductive material and flexible polymer have the advantages of good flexibility, light weight, easy processing and forming, and the conductive property of the material changes under strain stimulus, so it can be used as flexible strain sensing material. This paper reviewed the classification and characteristics of flexible strain sensing materials based on conductive polymer composites, introduced the strain response mechanism of different sensing materials in detail, and summarized the factors that affect the strain sensing performance of conductive polymer composites.

Key words: Conductive polymer composites, Flexible strain sensing material, Sensing mechanism, Strain sensing performance

中图分类号:

TQ31

李华, 朱雨田, 赵桂艳. 导电高分子基柔性应变传感材料研究进展[J]. 辽宁石油化工大学学报, 2022, 42(2): 44-49.

Hua Li, Yutian Zhu, Guiyan Zhao. Research Progress of Conductive Polymer Flexible Strain Sensing Materials[J]. Journal of Liaoning Petrochemical University, 2022, 42(2): 44-49.

参考文献 39

1	Wang R， Jiang N， Su J， et al. A bi⁃sheath fiber sensor for giant tensile and torsional displacements［J］. Advanced Functional Materials， 2017， 27： 1702134.
2	Amjadi M， Kyung K U， Park I， et al. Stretchable， skin⁃mountable， and wearable strain sensors and their potential applications： A review［J］. Advanced Functional Materials， 2016， 26： 1678⁃1698.
3	Zhou C G， Sun W J， Jia L C， et al. Highly stretchable and sensitive strain sensor with porous segregated conductive network［J］. ACS Applied Materials & Interfaces， 2019， 11（40）： 37094⁃37102.
4	Zhang Y， An Y， Wu L， et al. Metal⁃free energy storage systems： Combining batteries with capacitors based on a methylene blue functionalized graphene cathode［J］. Journal of Materials Chemistry A， 2019， 7： 19668⁃19675.
5	Zhai Y， Wang J， Gao Q， et al. Highly efficient cobalt nanoparticles anchored porous N⁃doped carbon nanosheets electrocatalysts for Li⁃O₂ batteries［J］. Journal of Catalysis， 2019， 377： 534⁃542.
6	Zhai W， Zhao S， Wang Y， et al. Segregated conductive polymer composite with synergistically electrical and mechanical properties［J］. Composites Part A： Applied Science and Manufacturing， 2018， 105： 68⁃77.
7	Zheng Y， Li Y， Li Z， et al. The effect of filler dimensionality on the electromechanical performance of polydimethylsiloxane based conductive nanocomposites for flexible strain sensors［J］. Composites Science and Technology， 2017， 139： 64⁃73.
8	Reddy R N， Reddy R G， Porous structured vanadium oxide electrode material for electrochemical capacitors［J］. Journal of Power Sources， 2006， 156（2）： 700⁃704.
9	Chen B Z， Qin Y， Weng D， et al. Design and synthesis of hierarchical nanowire composites for electrochemical energy storage［J］. Advanced Functional Materials， 2009， 19： 3420⁃3426.
10	Terlemezyan L， Ivanova B， Tacheva S. Electrically conductive polyaniline/polyoxymethylene blends［J］. European Polymer Journal， 1993， 29（7）： 1019⁃1023.
11	Wang H L， Toppare L， Fernandez J E， Conducting polymer blends： Polythiophene and polypyrrole blends with polystyrene and poly （bisphenol a carbonate）［J］. Macromolecules， 1990， 23（4）： 1053⁃1059.
12	Chen J， Zhang J， Luo Z， et al. Superelastic， sensitive and low hysteresis flexible strain sensor based on wavy⁃patterned liquid metal for human activities monitoring［J］. ACS Applied Materials & Interfaces， 2020， 12（19）： 22200⁃22211.
13	Oh J， Kim S， Lee S， et al. A liquid metal based multimodal sensor and haptic feedback device for thermal and tactile sensation generation in virtual reality［J］. Advanced Functional Materials， 2020， 31： 2007772.
14	Wei Q， Sun M， Wang Z， et al. Surface engineering of liquid metal nanodroplets by attachable diblock copolymers［J］. ACS Nano， 2020， 14（8）： 9884⁃9893.
15	Gao Z， Kong L， Jin R， et al. Mechanical， adhesive and self⁃healing ionic liquid hydrogels for electrolytes and flexible strain sensors［J］. Journal of Materials Chemistry C， 2020， 8： 11119⁃11127.
16	Rehman A， Zeng X. Interfacial composition， structure， and properties of ionic liquids and conductive polymers for the construction of chemical sensors and biosensors： A perspective［J］. Current Opinion in Electrochemistry， 2020， 23： 47⁃56.
17	Kim J S， Lee S C， Hwang J， et al. Enhanced sensitivity of iontronic graphene tactile sensors facilitated by spreading of ionic liquid pinned on graphene grid［J］. Advanced Functional Materials， 2020， 30： 1908993.
18	Zhao S， Li J， Cao D， et al. Percolation threshold⁃inspired design of hierarchical multiscale hybrid architectures based on carbon nanotubes and silver nanoparticles for stretchable and printable electronics［J］. Journal of Materials Chemistry C， 2016， 4： 6666⁃6674.
19	Xu R， Lu Y， Jiang C， et al. Facile fabrication of three⁃dimensional graphene foam/poly （dimethylsiloxane） composites and their potential application as strain sensor［J］. ACS Applied Materials & Interfaces， 2014， 6（16）： 13455⁃13460.
20	Shin M K， Oh J， Lima M， et al. Elastomeric conductive composites based on carbon nanotube forests［J］. Advanced Materials， 2010， 22： 2663⁃2667.
21	Huang J， Li D， Zhao M， et al. Highly sensitive and stretchable CNT‐bridged AgNP strain sensor based on TPU electrospun membrane for human motion metection［J］. Advanced Electronic Materials， 2019， 5： 1900241.
22	Costa P， Silvia C， Viana J C， et al. Extruded thermoplastic elastomers styrene⁃butadiene⁃styrene/carbon nanotubes composites for strain sensor applications［J］. Composites Part B： Engineering， 2014， 57： 242⁃249.
23	Mattmann C， Clemens F， Troster G. Sensor for measuring strain in textile［J］. Sensors， 2008， 8（6）： 3719⁃3732.
24	Zheng Y， Li Y， Dai K， et al. A highly stretchable and stable strain sensor based on hybrid carbon nanofillers/polydimethylsiloxane conductive composites for large human motions monitoring［J］. Composites Science and Technology， 2018， 156： 276⁃286.
25	He Z， Zhou G， Byun J H， et al. Highly stretchable multi⁃walled carbon nanotube/thermoplastic polyurethane composite fibers for ultrasensitive， wearable strain sensors［J］. Nanoscale， 2019， 11： 5884⁃5890.
26	Duan L， D'Hooge R， Spoerk M， et al. Facile and low⁃cost route for sensitive stretchable sensors by controlling kinetic and thermodynamic conductive network regulating strategies［J］. ACS Applied Materials & Interfaces， 2018， 10（26）： 22678⁃22691.
27	Lu L， Wei X， Zhang Y， et al. A flexible and self⁃formed sandwich structure strain sensor based on AgNW decorated electrospun fibrous mats with excellent sensing capability and good oxidation inhibition properties［J］. Journal of Materials Chemistry C， 2017， 5： 7035⁃7042.
28	Chen J， Zhu Y， Jiang W. A stretchable and transparent strain sensor based on sandwich⁃like PDMS/CNTs/PDMS composite containing an ultrathin conductive CNT layer［J］. Composites Science and Technology， 2020， 186： 107938.
29	Li H， Chen J， Chang X， et al. A highly stretchable strain sensor with both an ultralow detection limit and an ultrawide sensing range［J］. Journal of Materials Chemistry A， 2021， 9： 1795⁃1802.
30	Zhang R， Ying C， Gao H， et al. Highly flexible strain sensors based on polydimethylsiloxane/carbon nanotubes （CNTs） prepared by a swelling/permeating method and enhanced sensitivity by CNTs surface modification［J］. Composites Science and Technology， 2019， 171： 218⁃225.
31	Cao X， Wei X， Li G， et al. Strain sensing behaviors of epoxy nanocomposites with carbon nanotubes under cyclic deformation［J］. Polymer， 2017， 112： 1⁃9.
32	Lin L， Liu S， Zhang Q， et al. Towards tunable sensitivity of electrical property to strain for conductive polymer composites based on thermoplastic elastomer［J］. ACS Applied Materials & Interfaces， 2013， 5（12）： 5815⁃5824.
33	Yu Y， Peng S， Blanloeuil P， et al. Wearable temperature sensors with enhanced sensitivity by engineering microcrack morphology in PEDOT： PSS⁃PDMS sensors［J］. ACS Applied Materials & Interfaces， 2020， 12（32）： 36578⁃36588.
34	Liu H， Li Y， Dai K， et al. Electrically conductive thermoplastic elastomer nanocomposites at ultralow graphene loading levels for strain sensor applications［J］. Journal of Materials Chemistry C， 2016， 4： 157⁃166.
35	Wang S， Zhang X， Wu X， et al. Tailoring percolating conductive networks of natural rubber composites for flexible strain sensors via a cellulose nanocrystal templated assembly［J］. Soft Matter， 2016， 12： 845⁃852.
36	Liu H， Jiang H， Du F， et al. Flexible and degradable paper⁃based strain sensor with low cost［J］. ACS Sustainable Chemistry & Engineering， 2017， 5（11）： 10538⁃10543.
37	Park S J， Kim J， Chu M， et al. Highly flexible wrinkled carbon nanotube thin film strain sensor to monitor human movement［J］. Advanced Materials Technologies， 2016， 1： 1600053.
38	Pegan J D， Zhang J， Chu M， et al. Skin⁃mountable stretch sensor for wearable health monitoring［J］. Nanoscale， 2016， 8： 17295⁃17303.
39	Ren M， Zhou Y， Wang Y， et al. Highly stretchable and durable strain sensor based on carbon nanotubes decorated thermoplastic polyurethane fibrous network with aligned wave⁃like structure［J］. Chemical Engineering Journal， 2019， 360： 762⁃777.

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导电高分子基柔性应变传感材料研究进展

Research Progress of Conductive Polymer Flexible Strain Sensing Materials

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