辽宁石油化工大学学报

辽宁石油化工大学学报 ›› 2015, Vol. 35 ›› Issue (6): 16-19.DOI: 10.3696/j.issn.1672-6952.2015.06.004

• 石油化工 • 上一篇    下一篇

一种低凝点柴油抗磨剂的研制

丛玉凤1,王溪泽1,黄 玮1,杨贺群1,杨 光2   

  1. ( 1. 辽宁石油化工大学, 辽宁抚顺1 1 3 0 0 1; 2. 抚顺石化公司烯烃厂, 辽宁抚顺1 1 3 0 0 4)
  • 出版日期:2015-12-25 发布日期:2015-12-10
  • 作者简介:丛玉凤( 1 9 6 5 - ) , 女, 博士, 教授, 从事石油加工助剂与添加剂方面的研究; E - m a i l : y u f e n g c o n g 0 2@1 6 3. c o m
  • 基金资助:
    抚顺市科技攻关项目( F S K J HT 2 0 1 3 7 8) 。

The Research and Development of the Low Freezing Point Diesel Antiwear Agent

Cong Yufeng1,Wang Xize1,Huang Wei1,Yang Hequn1,Yang Guang2   

  1. (1.Liaoning Shihua University ,Fushun Liaoning 113001,China; 2.Olefin Plant of Fushun Petrochemical Company, Fushun Liaoning 113004,China)
  • Published:2015-12-25 Online:2015-12-10

PDF

摘要： 采用脂环酸与1, 3 - 丙二醇为原料, 甲苯为带水剂, 合成了一种柴油抗磨剂。考察了酸醇物质的量比,反应温度及反应时间对酯化率的影响, 并利用红外光谱对产物结构进行表征。结果表明, 当脂环酸与醇的物质的量比为2. 1∶1、 反应温度为1 5 0℃、 反应时间1. 0 0h时, 酯化率可达到9 6. 1%, 红外光谱结果表明合成的产物是目标产物。合成产物具有较高的运动黏度和较低的凝点, 添加质量分数为2 0 0μ g / g的合成产物到加氢柴油中, 可有效改善其抗磨性, 同时降低柴油的凝点。

关键词: 脂环酸, 抗磨剂, 酯化率, 抗磨性, 运动黏度

Abstract: The low freezing point diesel antiwear agent was prepared by using naphthenic acid and 1,3 propanediol as raw materials, toluene as water carrying agent. The effects of molar ratio, reaction time and temperature on the esterification rate of the product have been studied. Moreover, the product was characterized by IR spectra. The result show that the esterification rate could reach as high as 96.1% uner the condition of the mole radio of acid and glycol was 2.1∶1 at 150 ℃ for 1 h. IR spectra confirmed the formation of target product. The prepared product showed quite high kinematic viscosity and particularly low freezing point. When 200 μg/g of the antiwear agent was added to the diesel, the antiwear property could be enhanced and the freezing point of diesel was lowered down efficiently.

Key words: Naphthenic acid, Antiwear agent, Esterification rate, Antiwear property, Kinematic viscosity

引用本文

丛玉凤1,王溪泽1,黄 玮1,杨贺群1,杨 光2. 一种低凝点柴油抗磨剂的研制[J]. 辽宁石油化工大学学报, 2015, 35(6): 16-19.

Cong Yufeng,Wang Xize,Huang Wei,Yang Hequn,Yang Guang. The Research and Development of the Low Freezing Point Diesel Antiwear Agent[J]. Journal of Liaoning Petrochemical University, 2015, 35(6): 16-19.

使用本文

0
    /   /   推荐

导出引用管理器 EndNote|Ris|BibTeX

链接本文: http://journal.lnpu.edu.cn/CN/10.3696/j.issn.1672-6952.2015.06.004

               http://journal.lnpu.edu.cn/CN/Y2015/V35/I6/16



网站版权 © 2021《辽宁石油化工大学学报》编辑部

本系统由北京玛格泰克科技发展有限公司设计开发